NAUTILUS education

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NAUTILUS education • Text Sets Science Connected EFTA00805732 NAUTIL.US I TEXTSETS Introducing Nautilus Education The modern world has placed an unprecedented emphasis on science literacy. But most existing science texts do not emphasize literacy, and most literary texts don't have science. This Nautilus Education text set pamphlet is a beta product intended to fill this gap. It contains three groups of articles from the award-winning science magazine, Nautilus, each accompanied by lesson plans and guides for teachers. Key science concepts like genetics and astronomy are explored through narrative story telling and tailor-made artwork, letting science spill over its usual borders, and waking the imagination and interest of the student. This kind of literary science classroom material was designed to helps teachers satisfy the new U.S. common core and next gen standards but have global application. The relevant standards are listed in each lesson plan. Nautilus is looking for partners interested in using and further developing this kind of content. For more information, please write to [email protected]. —Michael Segal Editor-in-Chief About Nautilus Magazine Nautilus is a new kind of science magazine. Each monthly issue tackles a single topic in contemporary science using multiple vantage points, from biology and physics to culture and philosophy. We are science, connected. 2 EFTA00805733 NAUTILUS I TEXT SETS Contents Physics Biology 4 Astronomy & Space Travel 6 Roadmap to Alpha Centauri Pick your favorite travel mode— big,smakdark, oriwisted BY GEORGE MUSSER 12 Chemistry & Fuels 16 You are Made of Waste Searchingfor the ultimate example ofreeyeling? Look in the mirror BY CURT STAGER 22 Frack'er Up Naturalgasisshakingupthesearchfor green gasoline. BY DAVID BIELLO 0 O 28 Genetics & Human Health 30 Their Giant Steps to a Cure Battlingarareform ofmuseulardystrophy, afamilyfindsan activist leader, and hope BYJUDE ISABELLA 36 An Unlikely Cure Signals Hope for Cancer How "areeptional responders" are remlutionizing treatment for the deadly disease BY KAT MCGOWAN 3 EFTA00805734 NAUTILUS EDUCATION I BETA PRODUCT Astronomy&SpaceTravel How would we travel nearly five light years? This article explores different engineering solutions to the puzzle of taking a very, very, long trip, intertwining science-fiction goals with real world solutions. Students will explore fanciful applications of Newton's second law, and concepts of momentum, ions, and nuclear fusion. Lesson Plan Review vocabulary words in class. Have students read the article and answer the reading comprehension ques- tions for homework, as well as generate a discussion question of their own. In class, address any conceptual questions that the class might have. Have students write discussion questions on the board, along with the ones suggested in this document. Have students break up into small groups, each of which should address one of the discussionquestions. IS MIN Dedicate the remaining class time to completing one of the activities. 30-45 MIN Teacher's Notes: Roadmap to Alpha Centauri VOCAB WORDS Magnetic field: produced by a magnetic material or a current, a magnetic field will push or pull a moving charge or magnet that comes in contact with it. Ion: an atom in which the number of electrons and protons is unequal—thus, the atom is positive or negative. Momentum: the product of the mass and velocity of an object. Recoil: the backward momentum from a fired gun. Plasma: one of the four fundamental states of matter, composed of ions and electrons. Nuclear fusion: when two or more clusters of neu- trons and protons collide, forming a new nucleus and releasing energy. READING COMPREHENSION I. What does AU stand for? 2. How fast is Voyager I moving in miles per hour? 3. "The engine first strips propellant atoms [typi- cally xenon] of their outermost electrons." What is the charge of a stripped xenon atom? 4 EFTA00805735 NAUTIL.US I TEXT SETS 4. What concept is at work in the ion drive? (Hint: what is conserved?) S. What other travel options work on this principle? 6. How much momentum does an electron fired from a gun have? DISCUSSION QUESTIONS I. Why not take a traditional rocket to Alpha Centauri? 2. Which of the propulsion meturds listed is most likely to succeed? Would any be used together? 3. Would it be worth going if it took generations? 4. How far away is the next-nearest star? ACTIVITIES I. Research and create a brochure or ad enticing astronauts to make the nip. What would they eat? What psychological qualities would they need? If robots were sent, how would they be fixed? What kind of data could they expect to collect? 2. Propose another method of traveling to Alpha Centauri. ADDITIONAL MULTIMEDIA I. Voyager I Leaves the Solar System (The Guardian) I MIN 45 SEC A quick explanation of where Voyager I is, and how scientists know its location: httplAvww. voyager-I -leaves-solar-system-video 2. New Mars Rover Powered by Plutonium i)2 MIN 30 SEC An introduction to the nuclear battery on board the Mars Curiosity Rover, and the advantages of not using solar power (as with past missions): watch?v= I JOPWSztAcgEt WHERE THIS FITS IN THE CURRICULUM Structure and Properties ofMatier (HS-PSI -8)Develop models to illustrate the changes in the composition of the nucleus of the atom and the energy released during the processes of fission, fusion, and radioac- tive decay. Forces and Interactions (HS-PS2-I) Analyze data to sup- port the claim that Newton's second law of motion describes the mathematical relationship among the net force on a macroscopic object, its mass, and its acceleration. Forces and Interactions (HS-PS2-2) Use mathematical representations to support the claim that the total momentum of a system of objects is conserved when there is no net force on the system. Engineering Design (11S-E7S1-3) Evaluate a solution to a complex real-world problem based on priori- tized criteria and trade-offs that account for a range of constraints, including cost, safety, reliability, and aesthetics, as well as possible social, cultural, and environmental impacts. EFTA00805736 t7 • • e O EFTA00805737 MATTER I TECHNOLOGY Roadmap to Alpha Centauri Pick yourfavorite travel mode—big small, light, dark, or twisted BY GEORGE MUSSER VER SINCE THE DAWN of the space age, a quixotic subculture of physicists, engineers, and science-fiction writers have devoted their lunch hours and weekends to drawing up plans for starships, propelled by the imperative for humans to crawl out of our Earthly cradle. For most of that time, they focused on the physics. Can we really fly to the stars? Many initially didn't think so, but now we know it's possible. Today, the question is: Will we? Truth is, we already are flying to the stars, with- out really meaning to. The twin Voyager space probes launched in 1977 have endured long past their original goal of touring the outer planets and have reached the boundaries of the sun's realm. Voyager 1 is 124 astronomical units (AU) away from the sun—that is, 124 times farther out than Earth—and clocking 16 AU per year. Whether it has already exited the solar system depends on your definition of "solar sys- tem," but it is certainly way beyond the planets. Its instruments have witnessed the energetic particles and magnetic fields of the sun give way to those of interstellar space—finding, among other things, what Ralph McNutt, a Voyager team member and planetary scientist, describes as "weird plasma structures" beg- ging to be explored. The mysteries encountered by the Voyagers compel scientists to embark on follow- up missions that venture even deeper into the cosmic woods—out to 200 AU and beyond. But what kind of spacecraft can get us there? Going Small: Ion Drives NASA's Dawn probe to the asteroid belt has demon- strated one leading propulsion system: the ion drive. An ion drive is like a gun that fires atoms rather than bullets; the ship moves forward on the recoil. The sys- tem includes a tank of propellant, typically xenon, and a power source, such as solar panels or plutonium bat- teries. The engine first strips propellant atoms of their outermost electrons, giving them a positive electric charge. Then, on the principle that opposites attract, ILLUSTRATION BY CHAD HAGEN 7 EFTA00805738 NAUTILUS EDUCATION I BETA PRODUCT a negatively charged grid draws the atoms toward the back of the ship. They overshoot the grid and stream off into space at speeds 10 times faster than chemical rocket exhaust (and 100 times faster than a bullet). For a post-Voyager probe, ion engines would fire for 15 years or so and hurl the craft to several times the Voy- agers' speed, so that it could reach a couple of hundred AU before the people who built it died. Star flight enthusiasts are also pondering ion drives for a truly interstellar mission, aiming for Alpha Cen- tauri, the nearest star system some 300,000 AU away. Icarus Interstellar, a nonprofit foundation with a mis- sion to achieve interstellar travel by the end of the cen- tury, has dreamed up Project Tin Tin—a tiny probe weighing less than 10 kilograms, equipped with a min- iaturized high-performance ion drive. The trip would still take tens of thousands of years, but the group sees Tin Tin less as a realistic science mission than as a technology demonstration. Going Light: Solar Sails A solar sail, such as the one used by the Japanese IKAROS probe to Venus, does away with propel- lant and engines altogether. It exploits the physics of light. Like anything else in motion, a light wave has momentum and push- es on whatever surface it strikes. The force is feeble, but becomes noticeable if you have a large enough surface, a low mass, and a lot of time. Sunlight can accelerate a large sheet of lightweight material, such as Kapton, to an impressive speed. To reach the velocity need- ed to escape the solar system, the craft would first swoop toward the sun, as close as it dared—inside the orbit of Mercury—to fill its sails with lusty sunlight. Such sail craft could conceivably make the crossing to Alpha Centauri in a thousand years. Sails are limited in speed by how close they can get to the sun, which, in turn, is limited by the sail material's durability. Gregory Matloff, a City University of New York professor and longtime interstellar travel propo- nent, says the most promising potential material is gra- phene—ultrathin layers of carbon graphite. A laser or microwave beam could provide an even more muscular push. In the mid-1980s, the doyen of interstellar travel, Robert Forward, suggested piggy- backing on an idea popular at the time: solar-power satellites, which would collect solar energy in orbit and beam it down to Earth by means of microwaves. Before commencing operation, an orbital power sta- tion could pivot and beam its power up rather than down. A 10-gigawatt station could accelerate an ultra- light sail—a mere 16 grams—to one-fifth the speed of light within a week. Two decades later, start see- ing live video from Alpha Centauri. This "Starwisp" scheme has its dubious features—it would require an enormous lens, and the sail is so frag- ile that the beam would be as likely to fry it as to push it—but it showed that we could reach the stars within a human lifetime. 8 EFTA00805739 NAUTIL.US I TEXTSETS Going Big: Nuclear Rockets Sails may be able to whisk tiny probes to the stars, but they can't handle a human mission; need a microwave beam consuming thousands of times more power than the entire world currently generates. The best-developed scheme for human space travel is nuclear pulse propulsion, which the government -fund- ed Project Orion worked on during the 1950s and '60s. When you first hear about it, the scheme sounds unhinged. Load your starship with 300,000 nucle- ar bombs, detonate one every three sec- onds, and ride the blast waves. Though extreme, it works on the same basic principle as any other rocket—namely, recoil. Instead of shoot- ing atoms out the back of the rocket, the nucle- ar-pulse system shoots blobs of plasma, such as fireballs of tungsten. You pack a plug of tungsten along with a nuclear weapon into a metal capsule, fire the capsule out the back of the ship, and set it off a short distance away. In the vacuum of space. the explosion does less damage than you might expect. Vaporized tung- sten hurtles toward the ship, rebounds off a thick metal plate at the ship's rear, and shoots into space, while the ship recoils, thereby moving forward. Giant shock absorbers lessen the jolt on the crew quarters. Passengers playing 3-D chess, or doing whatever else interstellar passengers do, would feel rhythmic thuds like kids jumping rope in the apartment upstairs. The ship might reach a tenth the speed of light. If for some reason—solar explosion, alien invasion— we really had to get off the planet fast and we didn't care about nuking the launch pad, this would be the way to go. We already have everything we need for it. "Today the closest technology we have would be nuclear pulse," Matloff says. If anything, most people would be happy to load up all our nukes on a ship and be rid of them. Ideally, the bomb blasts would be replaced with con- trolled nuclear fusion reactions. That was the approach suggested by Project Daedalus, a '70s-era effort to design a fully equipped robotic interstellar vessel. The biggest problem was that for every ton of payload, the ship would have to carry 100 tons of fuel. Such a behemoth would be the size of a battleship, with a length of 200 meters and a mass of 50,000 tons. "It was just a huge, monstrous machine," says Kelvin Long, an Eng- lish aerospace engineer and co-founder of Project Icarus, a modern effort to update the design. "But what's happened since then, of course, is microelectronics, minia- turization of technology, nanotechnology. All these developments have led to a rethinking. Do you really need these mas- sive structures?" He says Project Icarus planned to unveil the new design in London in October 2013. Interstellar design- ers have come up with all sorts of ways to shrink the fuel tank. For instance, the ship could use electric or magnetic fields to scoop up hydrogen gas from inter- stellar space. The hydrogen would then be fed into a fusion reactor. The faster the ship were to go, the faster it would scoop—a virtuous cycle that, if maintained, would propel the ship to nearly the speed of light. Unfortunately, the scooping system would also pro- duce drag forces, slowing the ship, and the headwind of particles would cook the crew with radiation. Also, pure-hydrogen fusion is inefficient. A fusion-powered ship probably couldn't avoid hauling some fuel from 9 EFTA00805740 NAUTILUS EDUCATION I BETA PRODUCT Going Dark: Scavenging Exotic Matter Instead of scavenging hydrogen gas, Jia Liu, a physics graduate student at New York University, has pro- posed foraging for dark matter, the invisible exotic material that astronomers think makes up the bulk of the galaxy. Particle physicists hypothesize that dark matter consists of a type of particle called the neutralino, which has a useful property: When two neutralinos collide, they annihilate each other in a blaze of gamma rays. Such reactions could drive a ship forward. Like the hydrogen scooper, a dark-mat- ter ship could approach the speed of light. The prob- lem, though, is that dark matter is dark—meaning it doesn't respond to electromagnetic forces. Physicists know of no way to collect it, let alone channel it to produce rocket thrust. If engineers somehow overcame these problems and built a near-light-speed ship, not just Alpha Cen- tauri but the entire galaxy would come within range. In the 1960s astronomer Carl Sagan calculated that, if you could attain a modest rate of acceleration —about the same rate a sports car uses—and maintain it long enough, get so close to the speed of light that cross the galaxy in just a couple of decades of shipboard time. As a bonus, that rate would provide a comfortable level ofartificial gravity. On the downside, hundreds of thousands of years would pass on Earth in the meantime. By the time you got back, your entire civilization might have gone ape. From one perspective, though, this is a good thing. The tricks relativity plays with time would solve the eter- nal problem of too-slow computers. If you want to do some eons-long calculation, go off and explore some distant star system and the result will be ready for you when you return. The starship crews of the future may not be voyaging for survival, glory, or conquest. They may be solving puzzles. Going Warp: Bending Time and Space With a ship moving at a tenth the speed of light, humans could migrate to the nearest stars within a lifetime, but crossing the galaxy would remain a jour- ney of a million years, and each star system would still be mostly isolated. To create a galactic version of the global village, bound together by planes and phones, need to travel faster than light. Contrary to popular belief, Einstein's theory of rela- tivity does not rule that out completely. According to the theory, space and time are elastic; what we perceive as the force of gravity is in fact the warping of space and time. In principle, you could warp space so severely that shorten the distance you want to cross, like fold- ing a rug to bring the two sides closer together. If so, you could cross any distance instantaneously. You wouldn't even notice the acceleration, because the field would zero out g-forces inside the ship. The view from the ship windows would be stunning. Stars would change in col- or and shift toward the axis of motion. It seems almost mean-spirited to point out how far beyond our current technology this idea is. Warp drive would require a type of material that exerts a gravita- tional push rather than a gravitational pull. Such mate- rial contains a negative amount of energy—literally less than nothing, as if you had a mass of —50 kilograms. Physicists, inventive types that they are, have imagined ways to create such energy, but even they throw up their hands at the amount of negative energy a starship would need: a few stare worth. What is more, the ship would be impossible to steer, since control signals, which are restricted to the speed of light, wouldn't be fast enough to get from the ship's bridge to the propulsion system located on the vessel's perimeter. (Equipment within the ship, however, would function just fi When it comes to starships, it's best not to get hung up on details. By the time humanity gets to the point it might actually build one, our very notions of travel may well have changed. "Do we need to send full human?' asks Long. "Maybe we just need to send embryos, or maybe in the future, you could completely download yourself into a computer, and you can remanufacture yourself at the other end through something similar to 3-D printing." Today, a starship seems like the height of futuristic think- ing. Future generations might fi it quaint. ,€) george musser is a writer on physics and cosmology and authorof TheComplere Idiot :.Guide To String Theory(Alpha, 2008). He was a senior editor at Scientific American for 14 years and has won honors such as the American Institute of Physics ScienceWritingAward. 10 EFTA00805741 NAUTILUS EDUCATION I BETA PRODUCT Chemistry & Fuels The matter in our world is recycled. The pair of articles here explores how elements and atoms wend their way through space and time. Students will explore how chemical reactions usher ele- ments through their journeys. You Are Made of Waste illustrates, in five short vignettes, the lives of the elements that make up our teeth, fi breath, hair,andblood. Frac* ger Up isan in-depth look at the botched promise of biofuel—energy from cars made from renewable plant growth. In the "curriculum" section of the teacher's notes, you will find information on how these pieces can help fulfill requirements of the Next Generation Science Standards. Specifically, they make for entry points to—or a means of reinforcing —lessons on photosynthesis, chemical reactions, valence electrons, and energy. But more than that, these lessons will connect to the students' daily lives, and spark discussion. Lesson Plan: Ask students to read one or both of the articles for homework. Briefly introduce or review the vocabulary words in class. Assign all or a selection of the reading comprehension questions for the students to complete along with the reading, and ask them to come up with one question for further discussion. (Note that a couple of the questions for each article are redundant.) Start class with students raising any technical questions they might have about the readings. Ask them to contribute their discussion questions, and write these on the board, along with the questions provided in the teacher's notes. Ask the students to break into small groups; assign each group to address a question, and briefly present to the class for further discussion. 30-45 MIN In the following class time (or another class) have the students complete one or more of the activities in the teacher's notes in small groups. 30 MIN Teacher's Notes: You Are MadeofWaste VOCAB WORDS Mass: a physical property that describes an object's resistance to force. The mass of an object can be used to calculate its weight: (mass) x (gravitational force) = weight. Carbon: an element found in stars, planets, comets, as well as in all known living things. Radioactive decay: the process by which a nucleus ejects alpha particles, particles of ionizing radiation. A nucleus that does this is considered "unstable;" a substance that contains unstable nuclei is consid- ered "radioactive." This process usually only occurs in atoms heavier than iron. 12 EFTA00805742 NAUTIL.US I TEXT SETS Fusion: when two or more nuclei collide, fusing to make a new nucleus and releasing energy. This pro- cess usually only occurs in atoms lighter than iron. Chemical bond: an attraction between two or more atoms that allows them to form a substance of defi- nite chemical composition. Breaking these bonds requires energy. Petroleum: a "fossil fuel" that forms when organisms are crushed under rock and subjected to lots of pres- sure, and lots of time. Like the organisms it's made of, petroleum consists largely of carbon. 2. How does the story change the way you see your- self? Others? ACTIVITIES I. Pick an element not discussed in this article. Where else is it found? Where did it come from? 2. Draw a map or annotated illustration of all the places carbon goes in this article. Use outside research to complete a full picture of the carbon cycle. ADDITIONAL MULTIMEDIA READING COMPREHENSION I. I. "Each ofthose waste molecules is a carbon atom borne on two atomic wings of oxygen." Write out the chemical equation for the molecule described here. 2. "Organic" is used in two different ways in this piece. What are the two different definitions? 3. What does it mean for a chemical to be "highly reactive?" Identify oxygen's location on the peri- odic table, the group of atoms that it belongs to, and why they are considered "highly reactive." 4. Which elements on the periodic table are the least reactive? 5. "Fossil-based carbon dioxide molecules that are not soaked up by oceans or stranded in the upper atmosphere are eventually captured by plants, shorn of their oxygen wings, and woven into botanical sugars and starches." What is the process described here? (Hint: it is mentioned by name later in the piece.) Write down the equa- tion for this reaction. DISCUSSION QUESTIONS I. "Chemophobia" is the fear of chemicals. What are some chemophobic practices or products that we engage with? Are there good reasons to be afraid of chemicals? Whose air do you share? (It's OK To Be Smart, PBS) 3 m IN 30 SEC A video that explains how we breathe recycled air—including molecules of air exhaled by Ein- stein himself: 2. We Are Star Stuff segment (Carl Sagan's Cosmos) 8 MIN Carl Sagan explains how the elements of life were born in stars, evolved into simple organ- isms, then into us: intelligent creatures, capable of exploring the stars we came from: 3. The Microbes We're Made Of a MIN 30 SEC We're not just made of waste. We're made of trillions of other organisms. This video provides a quick exploration of the microbiome crucial to keeping our bodies working, and what we're doing to kill them: http:f/www.smithsonianmag. com/videos/category/3play_1/ the-microbes-were-made-of7?no-ist WHERE THIS FITS IN THE CURRICULUM Chemical Reactions (HS-PSI-2)Construct and revise an explanation for the outcome of a simple chemical reaction based on the outermost electron states of atoms, trends in the periodic table, and knowledge of chemical properties. I3 EFTA00805743 NAUTILUS EDUCATION I BETA PRODUCT Matter and its interactions (HS-PSI -I) Use the peri- odic table as a model to predict the relative properties of elements based on the patterns of electrons in the outermost energy level of atoms. From molecules to organisms: structure and pro- cases (HS-LSI-6) Construct and revise an explana- tion based on evidence for how carbon, hydrogen, and oxygen from sugar molecules may combine with other elements to form amino acids and/or other large carbon-based molecules. Ecosystems: Interactions, energy and dynamics (HS- LS-3) Construct and revise an explanation based on evidence for the cycling of matter and flow of energy in aerobic and anaerobic conditions. Teacher's Notes: Frack 'er Up VOCAB WORDS Ethanol: also found in beer and wine, it is a kind of biofuel that is sometimes added to gasoline for use in automobiles. Ethanol can be made from corn, potatoes, or green plants. Its chemical formula is CHICH2OH. Biofuel: a fuel made from plants or other organisms, in recent time. Biomass: material from recently living organisms. Organic compound: a molecule containing carbon. Hydrocarbon: Made ofjust hydrogen and carbon, these are the simplest kind of organic compound. Octane: a highly flammable hydrocarbon, and compo- nent of gasoline. Its chemical formula is Clan. Catalyst: a component of a chemical reaction that helps facilitate the reaction, but is not used up. READING COMPREHENSION I. "Plant biomass absorbs carbon dioxide as it grows." What is the name of the process by which plants do this? Look up and write down the chemical reaction. 2. A polymer is a chain of molecules. Identify a kind of polymer in the story, and the monomer that composes it. 3. Plants need carbon dioxide for photosynthesis. What are some of the sources for this carbon dioxide? DISCUSSION QUESTIONS I. Why is it advantageous for companies to be green? 2. Would you pay more for gas—or any other prod- uct, say a shirt—from a "green" company? What if some of that company's practices were just as questionable as those of "dark" companies? 3. How would the world change if gasoline could be made cheaply from natural gas? Should we consider this technology to be progress given that natural gas has it's own environmental consequences. ACTIVITIES Have students construct a timeline of fuel. Ask them to include dates mentioned from the story, and to research and add other relevant informa- tion: like the moment in history when organisms die, the life cycle of a tree that contributed the author's container of Primus fuel. 2. Draw a map or annotated illustration of all the plac- es carbon goes in this article. Use outside research to complete a full picture of the carbon cycle. 3. Write a 30-second ad convincing car drivers to pay a premium for green gasoline like Primus'. Include "fine print"—side effects, or caveats—as you see nerproiry. ADDITIONAL MULTIMEDIA 1. Algae (The Guardian) An interactive slide show that illustrates how biofuels are made out of algae: 14 EFTA00805744 NAUTIL.US I TEXT SETS active/2008/jun/26/algae 2. Bioprospecting (TED-Ed) 4 MIN An animated video introducing the concept of biofuels, and how they could help reduce reliance on our planet's limited supply of fossil fuels: prospecting-for-beginners-craig-a-kohn 3. The Microbes We're Made Of 2 MIN 30 SEC We're not just made of waste. We're made of trillions of other organisms. This video provides a quick exploration of the microbiome crucial to keeping our bodies working, and what we're doing to kill them: http://www.smithsonianmag. com/videos/category/3play_1/ the-microbes-were-made-of/?no-ist WHERE THIS FITS IN THE CURRICULUM Matter and energy in organisms and ecosystems (HS-LSI-5) Use a model to illustrate how photosyn- thesis transforms light energy into stored chemical energy. HistoryoftheEarth (HS-ESSI -6) Applyscientific reasoning and evidence from ancient Earth materials, meteorites, and other planetary surfaces to construct an account of Earth's formation and early history. Chemical reactions (HS-PSI -2)Construct and revise an explanation for the outcomes of simple chemical reactions based on the outermost electron state of atoms, trends in the periodic table, and knowledge of the patterns of chemical properties. Ecosystems: Interactions, energy and dynamics (HS- LS-3) Construct and revise an explanation based on evidence for the cycling of matter and flow of energy in aerobic and anaerobic conditions. IS EFTA00805745 MATTER I ENVIRONMENT You Are Made of Waste Searching for the ultimate example of recycling? Look in the mirror BY CURT STAGER YOU MAY THINK OF YOURSELF as a highly refined and sophisticated creature —and you are. But you are also full of discarded, rejected, and recycled atomic elements. Don't worry, though—so is almost everyone and everything else. Carbon: Your inky nails Look at one of your fingernails. Carbon makes up half of its mass, and roughly I in 8 of those carbon atoms recently emerged from a chimney or a tail- pipe. Coal-fired power plants, petroleum -guzzling cars, and kitchen gas stoves release carbon dioxide into the atmosphere. Each of those waste molecules is a carbon atom borne on two atomic wings of oxy- gen. Fossil-based carbon dioxide molecules that are not soaked up by the oceans or stranded in the upper atmosphere are eventually captured by plants, shorn of their oxygen wings, and woven into botanical sug- ars and starches. Eventually, some of them end up in bread, sweets, and vegetables, while others help form carbon-rich animal tissues, finding their way into meat and dairy products. Historically, atmospheric carbon dioxide was mainly replenished by volcanoes, forest fires, and biotic respiration. Today, one quarter of atmospheric CO2 is the result of fossil fuel combustion, whether it rose from smokestacks or was displaced from the oceans. (When fossil-fuel CO2 dissolves into ocean water, it displaces already-dissolved carbon dioxide derived from natural sources.) And because all of the carbon in your body derives from ingested organic matter, which in turn obtains it from the atmo- sphere, your fingernails and the rest of the organic matter in your body are built, in part, from emissions. ILLUSTRATIONS BY YUKOSHIMIZU 16 EFTA00805746 NAUTILUS I TEXT SE TS 17 EFTA00805747 NAUTILUS EDUCATION I BETA PRODUCT Radioactive Carbon-14: Your pearly whites When you smile, the gleam of your teeth obscures a slight glow from radioactive waste. During the late 1950s and early 1960s, atmospheric testing of thermo- nuclear weapons scattered so much radioactive car- bon-14 into the atmosphere that it contaminated vir- tually every ecosystem and human. Several thousand unstable radiocarbon atoms explode within and among your cells every second as their unstable nuclei under- go spontaneous radioactive decay. Some are the natu- ral products of cosmic rays that can turn atmospheric nitrogen into carbon-I4, while others result from the decay of unstable mineral elements that are found in soil. But many of them represent the echoes of ther- monuclear airbursts from the Cold War, finding their way into our water supply and meals. If they happen to disintegrate within your DNA, they can damage your genes. And many of them are bound up in your teeth. Unlike most of the atoms in your body, those embed- ded in your strong, stable tooth enamel have been with you ever since you ingested them through your umbili- cal cord and your infant feeding. If you were born dur- ing the early 1960s, you have more nuclear waste in your teeth than if you were born later, when soils and oceans had had time to bury radioactive atoms. In fact, forensic scientists use the proportion of bomb carbon in tooth enamel to determine the age of unidentified human remains. IS EFTA00805748 NAUTIL.US I TEXT SETS Oxygen: Your leafy breath The oxygen in your lungs and bloodstream is a highly reactive waste product generated by vegetation and microbes. Trees, herbs, algae, and blue-green bacte- ria split oxygen atoms out of water molecules during photosynthesis. They use most of the resultant gas for their own purposes, but thankfully some leaks out to sustain you. In fact it makes up about a fifth of the air you breathe. Your cells harness oxygen to release energy from chemical bonds in the food you consume. Oxygen absorbs electrons released by broken food molecules, which attract hydrogen ions, resulting in a molecular waste of your own making: metabolic water, which comprises one tenth of your body fluids. An average adult carries between 8 and 10 pounds of homemade wastewater within them, and 1 in 10 of your tears are the metabolic by-products of your breathing and eating. EFTA00805749 NAUTILUS EDUCATION I BETA PRODUCT Nitrogen: Your natural curls The next time you brush your hair, think of the nitrog- enous waste that helped create it. All of your proteins, including hair keratin, contain formerly airborne nitrogen atoms. But the nitrogen in air is biologically inert. For nitrogen to become a component of your hair, it has to be converted into a more accessible form. Nitrogen-fixing bacteria is one way that can happen. They live among the roots of beans, peas, and other legumes, consuming atmospheric nitrogen and releas- ing it as ammonia, a kind of microbial manure that fertilizes soil in which plants grow. When you eat a plant, you consume formerly atmospheric nitrogen. Every flash of lightning and every automotive spark plug emits a puff of nitrogen oxide, which can dissolve into raindrops and fall to earth as a form of fertilizer, again finding its way into food webs through plants. But most of the nitrogen in modem foods comes from urea and ammonium nitrate fertilizers artificially fixed by industrial processes. In ages past, the nitrogen in human hair came mainly from bacterial waste and lightning. But today, unless you eat a strictly organ- ic diet, you run your hairbrush through nitrogenous frameworks that are mostly of human origin. EFTA00805750 NAUTI L.US I TEXT SETS Iron: Your ancient blood When you cut yourself, the wreckage of stars spills out. Every atom of iron in your blood, which helps your heart shuttle oxygen from your lungs to your cells, once helped destroy a massive star. The fierce nuclear fusion reactions that set stars ablaze create the atomic elements of life. As the star ages, it fin- es progressively larger elements, such as silicon, sul- fur, and calcium. Eventually, iron atoms are fused. The problem is that iron fusion consumes as much energy as it produces, so it weakens the star. If the star is big enough, it will collapse in on itself, its outer layers rebounding against the dense inner core, and a supernova explosion will result. The blast sprays out iron at supersonic speeds, filling great swathes of space with debris that can form new solar systems. The iron in your frying pan, house keys, and blood is essentially cosmic shrapnel from the tremendous explosions that ripped through our galaxy billions of years ago. The same blasts also released carbon, nitrogen, oxygen, and other elements of life, which later produced the sun, the Earth, and eventually —you. ® curt stager is an ecologist and climate scientist at Paul Smith's College. He is the author of Deep Future: The Next i00,000 Years ofLife On Earth, and alsoco-hosts a weekly science program on North Country Public Radio. 21 EFTA00805751 EFTA00805752 NIAT TER :SI( t. Frack 'er Up Natural gas is shaking up the search for green gasoline BY DAVID BIELLO IAM SPEEDING DOWN New Jersey's highways, propelled by gasoline with a dash of ethanol, an alcoholic biofuel brewed from stewed corn ker- - nels. As I drive through the outskirts of the town- ship of Hillsborough, in the center of the state, I see that spring has brought with it a bounty of similar "bio- mass," as the fuel industry likes to call plants. Trees line the road and fresh-cut grass covers the sidewalks as I pull into the business park that is home to Pri- mus Green Energy—a company that has been touting a technology to transform such biomass into a green and renewable form of gasoline. But there's a hitch. The boom in hydraulic fracturing, or "fracking," a technique in which horizontal drilling and high-pressure jets of water are deployed to release gas trapped in sedimentary shale rock, has made natu- ral gas cheap and plentiful. That's not bad for Primus, whose technology can make gasoline from natural gas, biomass, or even low-grade coal, such as lignite or peat. This versatility makes Primus a potential part of what has been called the "olive economy" —companies that are neither bright green nor darkest black, but com- bine environmentally -friendlier technologies with old- er and dirtier ones in order to compete. In fact, Primus may become a leader in advancing this kind of technol- ogy. "We can be as dark as you want or as green as you want," says geologist, serial entrepreneur, and Primus salesman George Boyajian. In July, President Barack Obama gave a major speech on climate change that described natural gas as a "transition fuel" towards the "even cleaner energy economy of the future." But Primus's trajectory raises the question of whether natural gas is a boost on the road to a genuinely green fuel, or if it is prolonging our addiction to dirty modes of transport, and taking us on a detour from a low-carbon path. At the Primus headquarters, I first meet Primus's chief chemist Howard Fang in front of a prototype of a Primus conversion machine. Fang, who joined the company for what he calls his "semi-retirement," is ILLUSTRATION BY PETER &MARIA HOEY 23 EFTA00805753 NAUTILUS EDUCATION I BETA PRODUCT avuncular and black-haired. His interests are broad: He spends his spare time writing and reading history, and has authored books on conflict in the Middle East and the role of Christian missionaries in China. A lifetime in fuels chemistry left Fang with one burning question: "What is the real solution to the energy crisis?" His career at oil companies BP and ExxonMobil, and engine manufacturer Cummins, spanned not just one but two major energy upheav- als—the oil crisis of the 1970s and then its sequel in the first decade of the 2Ist century, which is arguably still ongoing. These experiences impressed on Fang the importance of securing the fuel supply in such a way as to avoid despoiling the environment. The solution, says the bespectacled chemist, is "nature- sourced biomass or natural gas converted effectively to gas or diesel." Primus's original idea was simple: take scrap wood or other biomass, turn it into pellets, and apply pres- sure and heat (700 degrees Celsius or more) to break it down into hydrogen and carbon monoxide. Then build this composite "syngas," shorthand for "synthet- ic gas," back up into whatever hydrocarbon product is desired—the molecules of eight carbon and 18 hydro- gen atoms known as iso-octane that are a measure of the quality of conventional gasoline, or the longer chains of similar hydrocarbons that comprise diesel or jet fuel. Because plant biomass absorbs carbon dioxide as it grows, the emissions produced by burning the biofuel should balance out overall—every molecule of CO2 emitted when the fuel is burned was previously absorbed by the plant that made the fuel. The story of the search for such green fuel is lit- tered with disappointments, however. Major compa- nies brew ethanol in large quantities in the United States. It is routinely added to gasoline (at levels of around 10 percent, on its way to 15 percent) as a way to improve combustion, reduce pollution, and support industrial corn farmers. But most ethanol is still made from the edible kernels of corn plants, instead of the inedible cellulose that was promised in the heady days of the mid-2000s, when Congress passed a spate of laws promoting biofuel production. Since 1978, the ethanol industry has enjoyed subsidies and tax credits to the order of 40 cents per gallon, and now produces an annual dead zone at the mouth of the Mississippi River each summer as a result of fertilizer washing off the endless cornfields of the Midwest. But ethanol is unlikely to ever fully replace conventional fossil fuels, since it is more difficult to transport, produces a frac- tion of the energy of oil, and would require engines to be refitted or replaced on a massive scale. Hence the interest in "drop-in" biofuels as a sub- stitute for conventional fuels in existing cars, planes, and trucks. The problem is not one of infrastructure, but chemistry: Companies must find a way to eco- nomically imitate and fast-track a process for which time and geology have done most of the work in con- ventional fossil fuels. The energy in these fuels is the pent-up power of ancient sunlight, which billions of photosynthetic microorganisms soaked up before dying, fossilizing, and turning into the hydrocarbon - rich stew we know as petroleum, and from which we refine gas, diesel, and jet fuel, among other products. In theory, then, it should be possible to turn the car- bohydrates and other chemicals that store energy for today's living things into the hydrocarbons we rely on for transportation. Potential routes to such "green crude" include algae, other photosynthetic organisms, and specialty microbes engineered to spit out hydrocarbons. Biofuel company Solazyme has a contract to supply United Airlines with 20 million gallons of algal jet fuel, and teamed up with a green fuel-station network to offer biodiesel in a test run in San Francisco's Bay Area. But it takes a lot of water—and a lot of energy to move that water around—in order to grow algae in large quan- tities, and tailor-making microbes is expensive at its current scale. As a result, companies are diversifying. Algal fuel producer Sapphire Energy is now focusing on isolating the genetic traits in the ancestors of all plants that might be usefully incorporated into other crops. Solazyme is making oils and specialty fats to sell at high margins to cosmetics and food companies, as is would-be microbial fuel-maker Amyris. The industry for "advanced biofuels is literally in its infancy," con- cedes Jonathan Wolfson, Solazyme CEO. The allure of Primus's technology is its promise to harness waste wood and other inedible biomass that would otherwise be thrown into landfills, and turn it into a renewable source of gasoline. Its "syngas to gasoline plus" process consists, essentially, of four 24 EFTA00805754 NA UTIL.US I TEXT SETS "We can be as dark as you want or as green auotovant," says Boyajian. chemical reactors. One turns the syngas into methanol. The next makes methanol into a molecule known as dimethyl ether, or DME in chemist-speak. In the third reactor, catalysts known as zeolites knit DME into gas- oline, in the most expensive and energy-intensive part of the process. The fourth reactor eliminates some of the unwanted byproducts that cause the resulting fuel to congeal at low temperatures. The key is the zeolites, porous minerals made up of aluminum, silicon, and oxygen that allow the desired chemical reactions to take place. Both Primus and a conventional oil refinery employ zeolites to manipu- late hydrocarbons. At an oil refinery, these catalysts help crack and sort hydrocarbons broken down from crude oil. At Primus, heat and pressure allow zeolites to build gasoline hydrocarbons from the smaller mol- ecules of syngas. Such "catalysts are a bit of a dark art," says Boyajian. He spars with Fang over whether or not the company will one day make their own. Fang does not accept Boyajian's need for secrecy, and would be more than happy to reveal all those dark arts—a pros- pect that makes the affable Boyajian nervous and tight- lipped. For now, the fledgling company buys the neces- sary catalysts off the shelf and must sign agreements not to examine these zeolites too closely. Using different catalysts in the reactors, Fang notes, the company could spit out diesel or jet fuel instead of gasoline. And for every 100 kilograms of syngas, he says, Primus can make 30 kilograms of gasoline or more, using a continuous looping system within the machine that eliminates the need for wasting energy to convert gases to liquids along the way. Little red containers of Fang-made gasoline record its charac- teristics, scrawled on masking tape affixed to the sides: low vapor pressure, a higher-than-average octane con- tent of around 93, and a favorable absence of sulfur or benzene. Oil prices have been rising over the last month, and are currently at more than $100 per barrel; the company estimates that its gasoline costs as little as that derived from oil at $65 per barrel—and could 25 EFTA00805755 NAUTILUS EDUCATION I BETA PRODUCT cost as little as $2 per gallon, or about half the price gas currently goes for at local pumps, to produce at a nth-sized facility, even though such an industrial plant would require a lot of capital to build. However, the machine Fang shows me is not run- ning on the biomass that Fang originally tested: wood chips, switchgrass, canary grass, miscanthus. Instead, it chums through natural gas, turning methane into syngas. Making long hydrocarbons from the single car- bon in methane molecules is "very easy," he assures me. But "natural gas is not true green," he concedes. "There is no benefit in [the reduction of] greenhouse gases. Biomass is still true green." Natural gas from the fracking boom has revolution- ized the global energy landscape—particularly in the United States, the world's biggest producer of shale gas. But it is also controversial. Gas burns cleaner, but it still produces around half the greenhouse emissions of its dirtier cousins like coal, not including the excess methane that leaks from fracking sites and the pipe- lines that transport the gas. Fracked gas can also con- taminate groundwater supplies. And while in 2012 it brought America's carbon footprint down to its low- est level in 20 years, relying on it in the long-term will make it hard to eliminate greenhouse gas emissions, as is required to combat climate change. As the price of natural gas slid in response to the glut of shale gas, Primus changed gears in mid-2012 to move away from biomass and to focus on making syngas from natural gas. This is not a new idea: Exx- onMobil built a plant in New Zealand in 1986 to turn natural gas into methanol and then gasoline, but aban- doned its efforts when the price of petroleum dropped dramatically in the mid I990s. Now, though, natural gas is cheap and attractive. Boyajian has a map of all the shale formations in North America tacked to the wall of his office. "The world is full of shale," he notes. An earlier version of Primus' machine, tuned to pro- cess biomass, sits swathed in silvery insulating tape in a locked and darkened lab. "Right now it is aban- doned," Fang says. The company insists that the state- ment doesn't apply to Primus's biomass efforts more generally. "This is the way to get to biofuels," says Pri- mus CEO Robert Johnsen, of the gas to gasoline pro- cess, through a tight smile. "Will we be the ones to get there? Maybe." The energy in these fuels is thepent-up power of ancient sunlight, which billions ofphotosynthetic microorganisms soaked up before dying. 26 EFTA00805756 NAUTI L.US I TEXT SETS Will natural gas be a bridge for Primus to green fuel, or will it be too cheap and attractive to resist as a permanent substitute for biomass? For the moment, the company seems keen to squeeze what it can out of the shale gale. With the help of more than $50 million in Israeli money, Primus is building a demonstration plant the size of a house near its headquarters in New Jersey, due to open this year. The location is off the map—even Google won't guide you there, as if it were some secretive skunk works facility, which is how the company likes to think of it. The plant will take natural gas from the local utility, run it through its proprietary set of chemical reactions and, on the far end, out of a spigot, will come gasoline— 12.7 gallons per hour at full capacity. The company's first commercial plant, due to start construction next year, will likely be located near a source of natural gas. Scaling up the technology this way will reduce the overhe