DTIC AD0784047: Improved Packaging of Water Purification Tablet

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TECHNICAL  REPORT  NO.  74-43 


IMPROVED  PACKAGING  OF  WATER  PURIFICATION  TABLET 


by 

Joseph  L.  Carney 
Environment  and  Survival  Branch 


April  1974 


Final  Report 


BERDEI 


APPROVED  FOR  PUBLIC  RELEASE;  DISTRIBUTION  UNLIMITED 

COUNTED  IN 

U.  S.  ARMY  LAND  WARFARE  LABORATORY 

Aberdeen  Proving  Ground,  Maryland  21005 


I 


20081017  384 


I 


The  findings  in  this  report  are  not  to  be  construed  as  an  official  Department 
of  the  Army  position  unless  so  designated  by  other  authorized  documents. 

The  contents  of  this  report  are  not  to  be  used  for  advertising,  publication, 
or  promotional  purposes.  Citation  of  trade  names  does  not  constitute  an 
official  endorsement  or  approval  of  the  use  of  such  commercial  products. 


DISPOSITION  INSTRUCTIONS 


Destroy  this  report  when  no  longer  needed.  Do  not  return  it  to  the 
originator. 


ii 


DEPARTMENT  OF  THE  ARMY 
U  S  ARMY  NATICK  LABORATORIES 
NATICK,  MASSACHUSETTS  01760 

in  reply  «*crrn  to 


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STSML-YPB 


15  October  107 '*• 


SUBJECT: 


Improved  Packaging  of  Iodine  Water  Purification 
Tablet,,  LWL  Technical  Report  T'o.*7k-L3 


TO:  Distribution  List  of  LWL  Technical  Report  T'o.  7^-^3 


1.  U.S.  Army  Land  Warfare  laboratory  Technical  Report  T'o.  Tli -LS , 
subject  as  above,  was  recently  distributed  to  your  Command  or 
Organisation. 


2.  Since  this  Laboratory'  has  the  responsibility  for  Sped 
MIL-W-283  (  ater  Purification  Tablet,  Iodine )  and  any  rose 
related  to  this  item,  the  inclosed  comment'  are  forwarded 
your  information  and  completeness  of  records. 


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STSNL-YPB 


15  October  197Jt 


MEMORANDUM  FOR  RECORD 

SUBJECT:  Improved  Packaging  for  Iodine  Water  Purification  Tablet 


1.  Reference  is  made  to  LWL  Task  No.  O5-S-69,  Final  Technical  Report 
7U-U3,  Subject:  Improved  Packaging  of  Water  Purification  Tablet,  by 
J. L.  Carney,  April  i97^. 

2.  Tli is  report  referenced  in'  paragraph  one  above  ie  a  culmination  cf 
efforts  by  LWL  to  show  that  the  Aclar  blister  package  is  equal  tc  the 
glass  bottle  as  a  packaging  material  for  the  iodine  water  purification 
tablet.  However,  for  the  sake  of  completeness,  certain  additional  in¬ 
formation  not  contained  in  this  report  should  be  emphasized. 

a.  The  tablets  used  in  the  \clar  package  vere  carefully  selected 
and  culled  by  the  contractor  prior  to  packaging.  Similarly,  tablets 

in  the  Aclar  packages  vere  selectively  chosen  before  and  after  environ¬ 
mental  storage  test  exposure  so  that  only  the  best  tablets  vere  used 
in  the  titration  and  solubility  tests.  This  vur.  done  intentionally 
in  order  to  avoid  any  tablet  deterioration  that  may  have  been  caused 
because  of  inadequate  heat  seals  in  the  Aclar  package.  In  contrast, 
no  preferred  selection  of  tablets  prior  to  bottling  or  after  the 
environmental  testing  vas  allowed  for  the  bottle.  The  bottle  had 
to  stand  the  test  as  it  came  from  the  normal  procurement  production' 
line,  and  would  therefore  contain  some  inferior  tablets.  Thus,  for 
the  purposes  of  these  tests, ,the  Aclar  package  vas  given  a  are f erred 
advantage  at  time  zero  as  to  the  quality  of  tablet  that  vas  packaged. 
Even  with  this  advantage,  the  Aclar  package  did  not  provide  any  signi¬ 
ficant  difference  in  iodine  tablet  potency  over  the  bottled  tablets. 

b.  Cost  estimates  for  the  mass  production  of  Aclar  package  vere 
conservatively  estimated  at  $0.18  per  package  (2k  tablets)  by  the 
contractor  in  1970  cf  which  $0.06  would  represent  the  cost  of  the 
iodine  tablet.  The  1970  cost  per  bottle  of  50  tablets  from  Van 
Brode  Milling  Co.  was  $0.12  and  included  labor,  shipping  costs,  etc. 


STSNL-YPB 


MEMORANDUM  FOR  RECORD 


15  October  l^jh 


ne^GSSlty  of  havinC  to  scale  the  equipment  up  from  a  oilot 

Mtielratcd  InCa^[-lalt°r^UCtl°n’  "°ny  COStly  f»««>  could  bo 

scarolS  ,°°  r0cent  sharP  riEe  «  the  cost  and 

( Pintle  polymers,  and  dependence  on  a  sinple  material 

estirnated  cost/unit  would  make  the  delivery  orice 
prohibitive.  The  final  cost  of  the  oackage  would  be  2'nwo  +u 

Sr  <*«*■ ')  —  protean  To^LZrr^t 


Morris  R.  Rogo*<s  AMIC  fat  ^ 

Research  Microbiologist  - - 

Biotechnology  Group 
Pollution  Abatement  Division 
Food  Sciences  Laboratory 


UNCLASSIFIED 


SECURITY  CLASSIFICATION  OF  THIS  PAGE  (Whu  Dm  EnCr.dJ 


REPORT  DOCUMENTATION  PAGE 

READ  INSTRUCTIONS 

BEFORE  COMPLETING  FORM 

1.  REPORT  NUMBER 

TECHNICAL  REPORT  NO.  74-43 

2.  GOVT  ACCESSION  NO. 

3.  RECIPIENT’S  CATALOG  NUMBER 

4.  TITLE  (mnd  Subtitle) 

IMPROVED  PACKAGING  OF  WATER  PURIFICATION 

TABLET 

S.  TYPE  OF  REPORT  &  PERIOD  COVERED 

Final  Report 

6.  PERFORMING  ORG.  REPORT  NUMBER 

7.  author^; 

Joseph  L.  Carney 

Environment  and  Survival  Branch 

8.  CONTRACT  OR  GRANT  NUMBERf®) 

9.  PERFORMING  ORGANIZATION  NAME  AND  ADDRESS 

US  Army  Land  Warfare  Laboratory 

Aberdeen  Proving  Ground,  MD  21005 

10.  PROGRAM  ELEMENT,  PROJECT,  TASK 

AREA  &  WORK  UNIT  NUMBERS 

LWL  Task  No.  05-S-69 

It.  CONTROLLING  OFFICE  NAME  AND  ADDRESS 

12.  REPORT  DATE 

April  1974 

13.  number  of  pages 

14 

14.  MONITORING  AGENCY  NAME  &  ADDRESS^//  different  from  Controlling  Office) 

15.  SECURITY  CLASS,  (of  this  report) 

Unclassified 

15a.  DECLASSIFICATION/ DOWNGRADING 

SCHEDULE 

16.  DISTRIBUTION  STATEMENT  (of  thia  Report) 

Approved  for  public  release;  distribution  unlimited 

17.  DISTRIBUTION  STATEMENT  (of  the  abetract  entered  In  Block  20,  It  different  from  Report) 

TECHNICAL  T  IF  • 

U  <i  1  J 

ilUEhdeen  i'l'-  v". (  : 

10.  SUPPLEMENTARY  NOTES  r* 

19.  KEY  WORDS  (Continue  on  reverse  aide  if  necessary  and  Identify  by  block  number) 

Iodine  Tablets 

Water  Purification 

Canteen  Water 

Field  Water 

20.  ABSTRACT  (Continue  on  reverse  side  If  necessary  and  Identify  by  block  number) 

The  new  method  of  packaging  the  iodine  tablets  consists  of  sealing  the 
individual  tablets  in  a  blister  sheet  and  packaging  two  blister  sheets  in 
an  overwrapper  packet.  The  blister  sheet  measures  1  3/4"  x  2  1/8”  and 
contains  12  transparent  blister  units  surrounded  by  a  steel  gray  color 
match  for  comparison  with  the  color  of  the  iodine  tablets.  The  new  simpli¬ 
fied  directions  for  use  are  printed  on  the  back  of  each  blister  sheet  and 
on  the  exterior  surface  of  the  overwrapper  packet. 

^ — iihmb 

DD  ,  JAN  73  1473  edition  OF  1  NOV  65  is  OBSOLETE  UNCLASSIFIED 


SECURITY  CLASSIFICATION  OF  THIS  PAGE  (When  Data  Entered ) 


TABLE  OF  CONTENTS 


Page 

REPORT  DOCUMENTATION  PAGE  (DD  FORM  1473)  iii 

INTRODUCTION  3 

DISCUSSION  4 

Initial  Evaluation  Quantity  Contract  4 

Environmental  Testing  of  Initial  Evaluation  Quantity  5 

Second  Evaluation  Quantity  Contract  7 

Environmental  Testing  of  Second  Evaluation  Quantity  8 

Field  Evaluation  8 

CONCLUSIONS  9 

REFERENCES  10 

APPENDICES 

A.  Partial  Analysis  of  139  Ranger  Questionnaires  A- 1 

from  Fort  Benning,  GA 

B.  Review  of  57  Responses  from  the  Special  Forces  B- 1 

Group  at  Fort  Devens,  MA 

C.  Comments  on  20  Questionnaires  from  Special  Forces  C-l 

Personnel  at  Fort  Gulick,  Canal  Zone 

DISTRIBUTION  LIST  11 


INTRODUCTION 


For  many  years  iodine  tablets  which  are  used  by  the  military  for  water 
purification  have  been  packaged  in  glass  bottles  of  50  tablets.  This  method 
of  packaging  has  serious  deficiencies  since  the  iodine  tablet  is  unstable 
when  exposed  to  air  and  is  ultrasensitive  to  moisture.  Deterioration  sets 
in  as  soon  as  a  bottle  is  opened  and  corrosion  of  the  metal  cap  which  often 
takes  place  during  storage  means  that  in  many  cases  the  tablets  have  already 
deteriorated  prior  to  the  initial  opening  of  a  bottle.  The  tablets  must  be 
used  according  to  directions  and  the  paper  label  containing  the  directions 
is  easily  removed  or  destroyed.  Furthermore  the  present  packaging  does 
not  provide  any  means  to  identify  the  color  change  from  steel  gray  to  white 
or  brown  which  is  the  visible  indication  of  deterioration. 

The  need  for  an  improved  method  of  packaging  iodine  water  purification  tablets 
has  been  recognized  for  many  years.  In  1963  a  study  report  by  Radiation 
Technology,  Inc.,  discussed  many  of  the  problems  relating  to  the  manufacture 
and  supply  of  the  tablets  (Ref.  1).  The  urgency  of  the  requirement  was  high¬ 
lighted  during  the  combat  in  Vietnam  as  discussed  in  two  reports  in  1967 
(Refs.  2  &  3).  The  report  by  the  Army  Concept  Team  in  Vietnam  (ACTIV)  (Ref. 

3)  noted  that  of  78  soldiers  interviewed,  only  40  soldiers  knew  that  the 
color  of  an  undeteriorated  purification  tablet  should  be  gray.  The  inter¬ 
views  established  that  many  soldiers  could  be  using  ineffective  tablets, 
unaware  that  the  water  they  were  drinking  had  not,  in  fact,  been  purified. 

A  1968  study  report  conducted  by  the  Naval  Medical  Field  Research  Laboratory, 
Camp  Lejeune,  NC  (Ref  4),  recommended  that  iodine  tablets  be  packaged  in  a 
manner  which  would  provide  long  time  protection  of  the  tablet,  means  for 
easily  dispensing  the  tablet  and  improved  means  of  inspecting  tablets  in 
storage. 


3 


DISCUSSION 


Recognizing  the  problem,  the  US  Army  Natick  Laboratories  (NLABS)  Natick,  MA 
initiated  development  to  find  a  better  method  of  packaging  the  iodine  water 
purification  tablets.  The  task  included  screening  seven  types  of  thin  film 
packaging  methods  to  determine  the  best  material  with  which  to  package  in¬ 
dividual  tablets.  The  iodine  water  purification  tablet  (FSN  6850-985-7166) 
contains  the  following  ingredients:  19.3  -  21.3  mg.  tetraglycine  hydro- 
periodide,  82-5  -  92.3  mg.  anhydrous  sodium  acid  phosphate  and  6.0  mg.  talc. 
The  tetraglycine  hydroperiodide  is  very  unstable  when  exposed  to  air,  rapidly 
passing  from  the  solid  state  to  iodine  vapor  which  is  highly  corrosive.  In 
addition,  the  iodine  compound  is  ultrasensitive  to  moisture  and  very  rapidly 
deteriorates  in  the  presence  of  even  a  very  small  amount  of  moisture.  These 
characteristics  made  it  very  difficult  to  find  a  suitable  packaging  material. 
From  the  survey,  only  one  material,  Aclar,  a  f luorohalocarbon  film  manufac¬ 
tured  by  the  Allied  Chemical  Company,  Morristown,  NJ  was  found  to  be  accep¬ 
table.  The  other  six  materials  were  either  attacked  by  free  iodine  or 
permeable  to  iodine  and  water  vapor. ^ 


The  NLABS  study  was  conducted  to  investigate  various  versions  of  strip 
packaging  and  blister  packaging  but  none  was  considered  acceptable  enough 
to  warrant  manufacturing  of  a  field  quantity.  In  this  study  no  attempt  was 
made  to  provide  a  steel  gray  color  match. 


Following  this  material  study,  and  as  a  result  of  funding  and  program 
priority  problems  which  prevented  further  work  by  NLABS,  the  US  Army  Land 
Warfare  Laboratory  (LWL)  initiated  a  task  to  continue  the  effort  to  improve 
the  tablet  packaging. 


Initial  Evaluation  Quantity  Contract 

A  contract,  DAAD05-70-C-0089 ,  was  awarded  to  the  Columbia  Research  Corporation, 
Gaithersburg,  MD  in  October  1969  for  development  and  production  of  a  quantity 
of  improved  packaging  of  the  water  purification  tablets. 

Based  on  the  NLABS  information  three  commercially  available  Aclar  films, 

22A,  22C  and  33C,  in  varying  thicknesses  were  considered  as  candidate 
materials  for  the  new  packaging.  Laminates  of  Aclar/polye thy lene/poly- 
vinylchloride  and  of  Aclar /polye thylene/aluminum  foil  were  also  included 
in  the  initial  screening  for  the  best  tablet  packaging  material.  The 
blister  sheet  type  of  packaging  was  determined  the  most  appropriate  and 
a  twelve  tablet  per  blister  sheet  quantity  was  established.  The  final 
blister  sheet  assembly  was  constructed  of  two  sheets  of  22A  Aclar  of  5  mil 
thickness  and  was  2-1/8"  x  1-3/4"  in  size.  The  tablets  were  sealed  between 
the  Aclar  sheets  by  a  grid  work  heat  seal  method.  A  2  mil  thick,  pressure 
sensitive  adhesive  backed,  steel  grey  acetate  label  applied  to  the  back  of 
the  blister  sheet  provides  the  desired  color  match  background  for  the  tablets. 


^■Personal  communication,  Sep  68  with  Dr.  Kwak  H.  Hu,  Natick  Laboratories 
Project  Officer  for  the  study.  There  was  no  published  report  of  the  study. 


4 


The  assembly  is  shown  at  the  top  of  Figure  1.  Tear  point  cut-outs  were 
provided  to  facilitate  the  tearing  open  of  the  Aclar  sheets  to  remove  each 
tablet. 

Although  Aclar  is  an  excellent  iodine  vapor  barrier,  it  does  not  provide 
the  individually  sealed  iodine  tablets  adequate  protection  against  water 
vapor  intrusion  during  long  term  storage.  It  was  decided  to  overwrap  two 
blister  sheets  with  a  heat  sealed  laminate  film  of  0.5  mil  Mylar/0.35  mil 
aluminum  foil/  3  mil  C79  polyolefin;  a  product  of  Continental  Can  Corporation, 
Baltimore,  MD  (Ref.  5).  in  addition  to  providing  the  needed  protection  against 
water  vapor  intrusion  the  overwrap  provides  protection  against  damage  to  the 
blister  sheets.  The  directions  for  use  of  the  tablet  and  manufacturing  data 
were  presented  on  the  overwrap.  See  lower  right  side  of  Figure  1  for  the 
overwrap  with  two  blister  sheets  partially  removed.  For  comparison  the 
standard  wax  sealed  bottle  of  50  iodine  tablets  is  shown  on  the  left  side 
of  the  figure. 

The  iodine  water  purification  tablets  used  in  this  development  program 
were  manufactured  by  Van  Brodie  Milling  Co.,  Inc.,  Clinton,  MA  in  accord¬ 
ance  with  Military  Specification  MIL-W-283F,  Water  Purification  Tablet, 

Iodine . 


Environment  Testing  of  Initial  Evaluation  Quantity 

NLABS  conducted  rough  handling  and  accelerated  laboratory  environmental 
storage  tests  of  the  new  package.  Additional  environmental  testing  was 
scheduled  to  be  conducted  at  Edgewood  Arsenal,  Edgewood ,  MD  but  was  can¬ 
celled  because  of  a  breakdown  in  the  environmental  chambers.  The  rough 
handling  tests  were  conducted  in  accordance  with  the  following  schedule: 


PHASE 

I: 

a. 

Condition  case  at  72°F,  50%  R.H. ,  for  24  hours 

b. 

Drop  test  from  21  inches  using  1  cycle  of  ASTM 
Standard  775,  Note  4. 

c. 

Vibrate  case  at  268  rpm,  1G,  for  1  1/2  hours. 

PHASE 

II: 

a. 

Condition  case  at  -20eF  for  24  hours 

b. 

Drop  test  from  21  inches  using  1  cycle  of  ASTM 
Standard  775,  Note  4. 

c. 

Vibrate  case  at  268  rpm,  1G,  for  1  1/2  hours 

Table  I  outlines  the  sampling  periods,  storage  conditions  and  the  number  of 
samples  agreed  upon  for  the  study.  Of  the  240  samples  withdrawn  for  eval¬ 
uation,  80  were  retained  for  package  evaluation,  while  160  were  tested  for 
solubility  and  titratable  iodine  test  using  the  procedures  described  in 
Military  Specification  MIL-W-283F.  The  standard  bottle  of  50  tablets  was 
subjected  to  the  same  storage  study  for  comparison. 


5 


Figure  1.  Standard  Bottle  and  New  Package 


6 


TABLE  I.  IODINE  TABLET  STORAGE  STUDY 


30  days  60  days  90  days  120  days 

Storage  Conditions_ A  B_ A  B_ A  BAB 


Initial  (240  for  A  &  B) 


140°F 

10%  r.h.  (static) 

240 

240 

240 

240 

240 

240 

240 

240 

(rough  handle  ) 

240 

240 

240 

240 

►“* 

o 

o 

o 

►n 

95%  r.h.  (static) 

240 

240 

240 

240 

240 

240 

240 

240 

(rough  handle  ) 

240 

240 

240 

240 

72°F 

50%  r.h.  (static) 

240 

240 

240 

240 

240 

240 

240 

240 

(rough  handle  ) 

240 

240 

240 

240 

-65°F 

(static) 

240 

240 

240 

240 

240 

240 

240 

240 

(rough  handle  ) 

240 

240 

240 

240 

A  -  Overwrapped  Packet  (two  blister  sheets/packet) 

B  -  No  Protective  Overwrap  (two  blister  sheets/unit) 

The  storage  study  was  terminated  by  NLABS  after  the  packets  were  exposed  for 
three  months  to  the  various  environmental  storage  conditions  because  the 
solubility  and  the  iodine  content  of  the  water  purification  tablets  were 
adversely  affected  by  exposure  to  high  temperature  and/or  relative  humiditv 
(see  Reference  6). 

Because  the  data  presented  in  Reference  6  seemed  contradictory  in  many  in¬ 
stances,  the  raw  data  of  the  storage  study  was  subjected  to  a  thorough 
statistical  analysis.  Although  some  of  the  data  was  statistically  unexplain¬ 
able,  it  was  concluded  that  the  unfavorable  results  of  the  storage  tests 
were  caused  by  two  principal  factors,  namely  unsatisfactory  iodine  tablets 
prior  to  packaging  and  lack  of  controlled  packaging  conditions  which  resulted 
in  moisture  being  trapped  in  the  cellulose  acetate  color  match  film  affixed 
to  the  back  of  each  blister  sheet. 

Second  Evaluation  Quantity  Contract 

Based  on  the  failure  analysis  of  the  first  quantity  of  packaged  tablets 
produced  and  tested,  a  fixed  price  contract  with  proper  changes  was  awarded 
to  Columbia  Research  Corporation  in  August  1971  (Reference  7).  This  contract, 
DAAD05-72-C-0028,  required  changes  in  the  pressure  and  dwell  time  of  the  heat 
sealing  cycle,  a  wider  heat  seal  in  the  grid,  sealing  tray  improvements  and 
stringent  moisture  control  of  components  and  the  assembly  atmosphere.  In 
addition  a  careful  selection  and  culling  of  the  available  tablets  was  made 

:wc  1*:: T  •  T,  IT"  •  .  ■ 


.u'Ek’ 


7 


in  an  attempt  to  prevent  random  tablet  failure  confusing  the  subsequent  test 
data . 


Environmental  Testing  of  Second  Evaluation  Quantity 

The  packets  of  iodine  tablets  produced  in  the  second  evaluation  quantity 
contract  were  subjected  to  accelerated  laboratory  environmental  tests  in  a 
similar  manner  as  were  the  packets  of  the  initial  evaluation  quantity.  Data 
over  a  six  month  storage  test  period  was  tabulated  (see  Reference  8).  Anal¬ 
ysis  of  the  raw  data  of  this  storage  study  by  USALWL  Research  Analysis  Office 
showed  that  there  was  no  significant  difference  in  the  iodine  tablet  potency 
whether  stored  in  bottles  or  blister  sheets  in  overwrapped  packets. 


Field  Evaluation 

On  19  July  1973  a  meeting  was  held  between  representatives  of  Office  of  The 
Surgeon  General,  NLABS  and  LWL  and  it  was  agreed  that  the  environmental 
storage  test  results  showed  that  there  was  no  significant  difference  between 
the  standard  bottle  packaging  system  and  the  LWL  blister  sheet  in  overwrapped 
packet  packaging  system.  It  was  also  agreed  that  LWL  should  proceed  with 
field  evaluations. 

A  partial  analysis  of  139  questionnaires  completed  by  one  class  of  Ranger 
Students  is  enclosed  as  Appendix  A.  A  review  of  57  responses  from  the 
Special  Forces  Group  at  Fort  Devens ,  MA ,  is  enclosed  as  Appendix  B.  A 
letter  of  comments  representing  the  general  consensus  of  15  of  the  20 
Special  Forces  personnel  at  Fort  Gulick,  Canal  Zone,  is  enclosed  as  Appendix  C. 


8 


CONCLUSIONS 


1.  There  is  no  significant  difference  in  iodine  tablet  potency  whether 
stored  in  bottles  or  blister  sheets  in  overwrapped  packets.  Based  upon  tablet 
discoloration,  the  evaluation  results  were  almost  identical.  One-third  of  the 
reports  noted  discoloration  in  each  case. 

2.  Evaluation  under  field  conditions  showed  that  the  bottle  was  pre¬ 
ferred  over  the  packets.  The  troops  stated  that  it  was  more  difficult  to 
extract  tablets  from  the  blister  sheet  and  that  the  tablets  were  easily 
crushed  or  broken. 


9 


REFERENCES 


1#  "Production  Study,  Water  Purification  Tablets,  Iodine,"  Radiation 
Technology,  Inc.,  Washington,  DC,  Contract  DA-33-031-AMC-106(T) ,  2  December 
1963. 

2.  Weidenkopf,  Stanley  J. ,  'Military  Water  Supply  Problems  in  Vietnam," 
Mil.  Med.,  132:443-448,  June  1967. 

3.  "Water  Supply  in  the  Republic  of  Vietnam,"  ACTIV  (ACL-22F) , 

6  December  1967. 

4.  Hurst,  Ned  S.  and  Bird,  James,  S.,  "The  Effect  of  Selected  Soft  Drink 
Mixes  on  the  Germicidal  Properties  of  Iodine  Tablets,"  Naval  Medical  Field 
Research  Laboratory,  Camp  Lejeune,  NC,  Bureau  of  Medicine  and  Surgery,  Navy 
Department,  MF  12.524.007-8007.1,  Vol.  XVIII,  No.  14,  August  1968. 

5.  Brown,  Denny  F.  and  Derick,  Charles  T. ,  "A  Blister  Sheet  and  Pouch 
Overwrapper  Package  for  the  Iodine  Water  Purification  Table t ,"  Final  Report, 
Contract  No.  DAAD03-70-C-0089 ,  AD  #733921,  Columbia  Research  Corp., 
Gaithersburg,  MD  20760,  October  1961. 

6.  US  Army  Natick  Laboratories,  AMXRE-PRIM  Laboratory  Report  70-F-8, 

Subject:  Titratable  Iodine  and  Solubility  Analyses  of  the  Iodine  Water 

Purification  Tablet  (MIL-W-283)  Packaged  in  an  Experimental  Aclar  22A  Blister 
Sheet  and  Pouch  Overwrapper  as  furnished  by  USALWL  Under  Contract  No. 
DAAD03-70-C-0089  with  Columbia  Research  Corporation,  Gaithersburg,  Maryland, 

4  March  1971. 

7.  Derick,  Charles  T.  and  Brown,  Denny  F.,  Development  of  an  Improved 
Blister  Sheet  and  Pouched  Overwrapper  Package  for  Iodine  Water  Purification 
Tablets,"  Final  Report,  Contract  No.  DAAD05-72-C-0028 , 

Columbia  Research  Corp.,  Gaithersburg,  MD  20760  (Tech.  Report  No.  LWL-CR- 
05-S-69). 

8.  US  Army  Natick  Laboratories,  AMXRE-PRLM  Final  Laboratory  Report 
72-F-ll,  Subject:  Titratable  Iodine  and  Solubility  Analysis  of  an  Improved 
Aclar  Blister  Packed  Iodine  Water  Purification  Tablet  2  March  1973, 

(USALWL  Task  No.  05-S-69). 


10 


DEPARTMENT  OF  THE  ARMY  MAJ  Spies/ jp/5-6768 

RANGER  DEPARTMENT 
75TH  INFANTRY  (RANGER) 

UNITED  STATES  ARMY  INFANTRY  SCHOOL 
Fort  Benning,  Georgia  31905 


ATSH-R-0 


31  January  1974 


SUBJECT:  Packaging  of  Iodine  Water  Purification  Tablet 


TO:  Commander 

US  Army  Land  Warfare  Laboratory 
ATTN:  AMXLW-DES/Mr.  Carney 
Aberdeen  Proving  Ground,  MD  21005 


1.  Per  informal  agreement  of  Ranger  Department,  USAIS,  with  Mr.  Carney, 
your  office,  the  durability  test  of  the  blister  package  for  iodine  tablets 
is  completed. 

2.  Only  one  class  of  Ranger  students  participated  in  this  test.  A 
questionnaire  from  each  student  who  graduated  (136)  is  being  forwarded 
along  with  quantities  of  used  bottles  and  blister  sheets  to  your  office 
under  separate  cover . 

3.  Ranger  students,  when  cold  and  wet,  experienced  difficulty  opening 
the  blister  sheet.  They  generally  preferred  the  bottle  over  the  blister 
sheet.  It  was  suggested  that  the  current  bottle  top  be  painted  grey  (to 
match  a  usable  tablet)  instead  of  black. 

FOR  THE  DIRECTOR: 


FRANK  H.  SCOTT 
LTC,  Infantry 
Deputy  Director 


A- 2 


APPENDIX  A 


PARTIAL  ANALYSIS  OF  139  RANGER  QUESTIONNAIRES 
FROM  FORT  BENNING ,  GA 


AMXLW-RAO 


2S  February  1974 


MEMORANDUM  FOR  RECORD 

SUBJECT:  Review  of  Questionnaires  Received  from  Ranger  Evaluation  of  Iodine 
Tablet  Blister  Pack 

1.  As  requested  by  Mr.  J.  Carney,  Project  Officer  on  LW L  Task  No.  05-S-69,  the 
data  from  139  Ranger -completed  questionnaires  have  been  examined  and  a  partial 
analysis  of  the  data  has  been  accomplished. 

2.  It  is  quite  apparent  from  the  questionnaire  data  that  the  blister  pack  with 
overwrap  is  much  more  difficult  to  handle  (while  extracting  tablets)  than  the 
bottle.  The  handling  problem  is  undoubtedly  the  major  factor  in  the  71%  overall 
preference  for  the  bottle  over  the  blister  pack.  It  should  be  recognized,  however, 
that  this  field  evaluation  was  probably  conducted  in  an  environment  where  iodine 
tablets  were  not  always  required  (There  was  one  comment  to  that  effect.).  Other 
questions  were  also  raised  as  to  the  validity  of  this  evaluation,  but  this  docs 
not  mean  that  the  overall  results  should  be  discounted;  rather,  it  does  mean  that 
any  additional  evaluation  underway  should  be  continued  and  any  decision  to  con¬ 
tinue  or  discontinue  the  LWL  task  should  be  based  upon  additional  evaluations , 
together  with  the  Ranger  evaluation. 

3.  One  of  the  important  findings  is  that  there  are  two  "mechanical"  problems  with 
the  LWL  blister  package.  There  were  22  final  comments  that  tablets  within  the 
blister  packs  were  crushed  or  broken.  This  condition  occurred  as  a  result  of  both 
opening  the  blister  pack  (due  to  hand  pressure)  and  storage  on  the  person.  For 
example,  it  was  noted  that  tablets  in  blister  packs  should  not  be  carried  in  back 
pockets  because  they  would  be  crushed  when  one  sat  down.  Hence,  it  appears  that 
the  bottle  provides  superior  physical  protection  for  the  tablets  over  the  blister 
pack  both  during  tablet  extraction  and  transport. 

4.  One  third  of  the  questionnaires  which  gave  tablet  condition  information  noted 
one  or  more  discolored  tablets  from  the  LWL  packages.  The  equivalent  information 
on  the  bottle  is  not  as  reliable  because  the  question  was  difficult  to  interpret 
on  this  point,  but  the  percentage  of  questionnaires  noting  discolored  tablets 
from  the  bottles  was  almost  identical,  i.e.,  32%.  However,  there  were  eight  dif¬ 
ferent  questionnaires  (6%  of  total)  in  which  it  was  reported  that  whole  bottles 
of  tablets  went  bad. 

5.  It  appears  that  the  only  unanswered  question  which  bears  on  the  disposition 
of  this  task  (05-S-69)  is:  "Are  bottles  a  significantly  inferior  storage  con¬ 
tainer  compared  with  the  LWL  package  in  operational  usage?"  That  is,  is  the 
health  protection  factor  down  when  tablets  from  a  previously  opened  bottle  are 
used?  This  question  can  be  partially  answered  in  terms  of  tablet  appearance- -and 


AMXLW-RAO 


25  February  1974 


SUBJECT:  Review  of  tyjcstionnaires  Received  from  Ranger  Evaluation  of  Iodine 


Tablet  Blister  Pack 


could  be  partially  resolved  in  favor  of  the  bottle--with  a  color  match  indicator 
for  the  bottle  as  discussed  previously  by  Natick  personnel  and  as  noted  by  comments 
m  the  questionnaires  from  the  Ranger  exercise.  In  fact,  the  safety  aspects  of 
the  bottle  might  be  completely  resolved  by  increasing  the  basic  load  of  bottles 
and  directing  the  individual  soldier  to  open  a  new  bottle  whenever  there  is  reason 
to  doubt  the  quality  of  tablets  in  a  previously  opened  bottle.  However,  the  eco- 
nomics  and  logistics,  of  such  a  direction  could  possibly  rule  unfairly  in  favor  of 
the  blister  package. 

6.  In  summary,  the  results  of  the  Ranger  field  evaluation  tend  to  negate,  by  new 
findings,  the  operational  superiority  of  the  LWL  blister  package  over  the  bottle 
for  iodine  tablet  storage  which  had  been  previously  acceded  to  by  Natick  personnel. 


Research  Analysis  Office 


CF: 


CO/TD 
C,  MOD 


A/C,  I)ED 

C^ks 

in.  Carney 


APPENDIX  B 


REVIEW  OF  57  RESPONSES  FROM  THE  SPECIAL  FORCES  GROUP 
AT  FORT  DEVENS,  MA 


DEPARTMENT  OF  THE  ARMY 
Company  A,  3rd  Battalion 

10th  Special  Forces  Group  (Airborne) ,  1st  Special  Forces 
Fort  De-rens,  Massachusetts  01433 


SF33-AC  25  February  1974 

SUBJECT:  Summary  Report  of  Water  Purification  Blister  Sheet  Packets 


CDR,  U.S.  Army  Sand  Warfare  Laboratory 
ATTN :  AMXLW-DES/  Mr.  J.L.  Carney 
Aberdeen  Proving  Ground  MD  21005 


1.  Section  1  and  II  of  the  Command  and  User  Questionnaire  were  comnleted 
on  the  same  day  for  control. 

2.  to  unopened  bottles  or  blister  sheet  packets  were  retained. 

3.  Concensus  of  opinion  was  in  favor  of  the  bottled  water  ourif'ication 
packets  over  the  blister  sheet  packets.  (39  for  bottle,  18  for  packets) 

4.  The  bottle  system  is  definitely  easier  to  use  in  cold  weather  and  can 
be  used  wearing  gloves.  The  bottle  is  easier  to  keep  with  the  canteen 

by  taping  to  the  cap  strap  of  the  canteen  or  in  the  pouch  included  on  the 
later  model  canteen  covers.  The  blister  sheet  packet  has  the  two  advantages 
of  a  color  comparison  capability  and  individual  compartmentalization.  The 
color  comparison  capability  could  be  applied  to  the  bottle  by  coloring  the 
inside  of  the  cap  for  comparison.  The  individual  compartmentalization 
advantage  would  seem  to  be  marginal  considering  the  disadvantages  of  bulkier 
and  more  fragile  packing  for  the  blister  sheet. 

CHARLES  W.  KARWAN 
CPT,  Infantry 
S3  Officer 


B-2 


AMXDV-RAO 


8  March  1971 


MEMORANDUM  FOR  RECORD 

SUBJECT:  Review  of  Second  Set  of  Operational  Test  Results  on  Iodine  Tablet  Pack¬ 
aging 

1.  Reference.  RAO  } IFR ,  AMXLW-RAO,  25  Feb  74,  subject:  Review  of  Questionnaires 
Received  from  Ranger  Evaluation  of  Iodine  Tablet  Blister  Pack. 

2.  A  second  set  cf  completed  questionnaires  was  received  on  the  operational  eval¬ 
uation  of  the  packaping  of  the  iodine  tablet  (E§S  Task  05-S-69).  This  set  of 
responses  came  from  the  Special  Forces  Group  at  Fort  Devens,  MA.  Although  there 
were  some  basic  differences  between  the  results  of  the  two  tests,  two  of  the  key 
indicators  were  nearly  identical;  viz.,  the  preference  to  carry  blister  packs  was 
3b*  in  the  SF  test  compared  with  37*  in  the  first  evaluation  by  the  Rangers  (refer¬ 
enced  MFR),  and  the  overall  preference  for  the  blister  pack  was  31%  for  the  SF 
test  compared  with  29%  for  the  Ringer  evaluation. 

3.  rhe  cross -section  of  personnel  on  the  SF  test  was  completely  different  from  the 
Ranger  evaluation,  where  the  personnel  evaluating  the  packaging  were  all  recent 
West  Point  graduates.  In  the  Fore  Devens  evaluation,  the  personnel  were  primarily 
enlisted  men  (46)  with  service  ranging  from  one  year  to  22  years.  The  11  officers 
involved  had  varied  lengths  of  service  and  their  ranks  ranged  fran  2d  LT  to  MAJ. 

4.  The  basic  comments  in  this  evaluation  were  much  the  same  as  in  the  previous 
evaluation,  i.e.,  the  men  had  more  difficulty  in  opening  the  blister  pack  than  in 
opening  the  bottle.  They  found  that  tablets  were  crushed  and  packages  were  cracked 
while  carrying  the  blister  packs,  and  tablets  were  crushed  in  the  act  of  openin'? 
the  blister  packs.  Again,  there  were  comments  on  the  difficulty  of  opening  the 
packages  in  cold  weather  and  at  night. 

5.  I he  basic  difference  between  the  results  of  the  two  evaluations  was  the  number 

of  reported  cases  of  bad  tablets  in  the  blister  package;  there  were  only  six  renorteu 
cases  of  bad  tablets  (11%)  compared  with  53%  in  the  first  evaluation.  The  reported 
cases  of  bad  tablets  in  the  bottle  was  down  slightly  from  35%  to  30%.  However, 
there  were  no  reported  cases  of  entire  bottles  of  tablets  going  bad. 

6.  Although  this  second  evaluation  makes  the  proper  disposition  of  the  packaging 
task  (05-S-69)  much  clearer,  i.e.,  it  tends  to  lend  further  support  to  task  termina¬ 
tion  »  if  will  be  interesting  to  find  out  what  happens  in  the  evaluation  in  Panama 
where  the  cold  factor  is  not  present  and  the  moisture  problem  could  be  greater. 


CF: 

CO/IT) 

C,  MOD 
A/C,  DED 
C,  E5S 
Carney 


ELLSWORTH  B.  SHANK 
Research  Analysis  Office 


B-3 


APPENDIX  C 


COMMENTS  ON  20  QUESTIONNAIRES  FROM  SPECIAL  FORCES  PERSONNEL 
AT  FORT  GULICK,  CANAL  ZONE 


DEPARTMENT  OF  THE  ARMY 

HEADQUARTERS,  SECURITY  ASSISTANCE  FORCE  FOR  LATIN  AMERICA 
SPECIAL  FORCES  BATTALION,  7TH  SPECIAL  FORCES  GROUP  (AIRBORNE),  1ST  SPECIAL  FORCES 

FORT  GULICK,  CANAL  ZONE 


SCARSF-SD 


27  March  1974 


SUBJECT:  Water  Purification  Tablet  Test 


Commander 

U.S.  Army  Land  Warfare  Laboratory 
ATTN:  AMXLW-DES/Mr  J.C.  Carney 
Aberdeen  Proving  Grounds,  Maryland  21005 


1.  Subject  test  was  completed  by  members  of  Co  A,  3/7th  SF  Gp  (Abn) ,  1st 
SF,  Fort  Gulick,  Canal  Zone  during  the  period  4  Feb  74  thru  14  Mar  74. 
Notation  should  be  made  of  the  time  in  service  of  the  majority  of  tested 
personnel  (8  to  18  years).  Unused  tablets  accompany  this  letter. 

2.  Most  notable  observations  were  made  by  CPT  Kimball  and  SFC  Taylor. 
Comments  on  the  tablets  as  listed  below  represent  the  general  consensus 
of  fifteen  (15)  of  the  twenty  (20)  personnel  tested,  whom  preferred  the 
bottle . 

a.  Packet  was  too  difficult  to  open. 

b.  Tablets  in  packet  were  often  crushed. 

c.  Packet  was  too  easily  lost. 

d.  Packet  was  hard  to  attach  to  canteen  cover  where  it  serves  as  a 
reminder  of  use. 

e.  Packet  dissolves  when  exposed  to  Army  Insect  Repellent. 

f.  Packet  is  impossible  to  open  if  one  is  wearing  gloves  or  a  bandage. 

3.  Three  individuals  favored  the  packet  because  it  was  not  bulky  and  could 
be  conveniently  placed  out  of  the  way. 

4.  Two  personnel  had  nothing  of  value  to  contribute  to  the  testing  phase. 
FOR  THE  COMMANDER: 


Major,  Infantry 
Adjutant 


C-2 


DISTRIBUTION  LIST 


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