ENVIRONMENTAL

NALL ENVIRONMENTAL ANALYSIS LABORATORY July 03, 2013 Brice Gordon Zorro Ranch 49 Zorro Rancho Rd. Stanley, NM 87056 TEL: (505) 934-2809 FAX RE: Drinking Water ZDC Dear Brice Gordon: 1101! Erteirrossental Andy= Laboratory 4901 Ilawdras Nb Albuquerque. NM87109 TEL: 505-345-3975 FAX 505-3454107 Websile: yr.Meneaegml. OrderNo.: 1306581 Hall Environmental Analysis Laboratory received 4 sample(s) on 6/13/2013 for the analyses presented in the following report. These were analyzed according to EPA procedures or equivalent. To access our accredited tests please go to www.hallenvironmental.com or the state specific web sites. In order to properly interpret your results it is imperative that you review this report in its entirety. See the sample checklist and/or the Chain of Custody for information regarding the sample receipt temperature and preservation. Data qualifiers or a narrative will be provided if the sample analysis or analytical quality control parameters require a flag. When necessary, data qualifers are provided on both the sample analysis report and the QC summary report, both sections should be reviewed. All samples are reported, as received, unless otherwise indicated. Lab measurement of analytes considered field parameters that require analysis within 15 minutes of sampling such as pH and residual chlorine are qualified as being analyzed outside of the recommended holding time. Please don't hesitate to contact HEAL for any additional information or clarifications. Sincerely, Andy Freeman Laboratory Manager 4901 Hawkins NE Albuquerque, NM 87109 EFTA01124465 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306581 Date Reported: 7/3/2013 CLIENT: Zorro Ranch Project: Drinking Water ZDC Lab ID: 1306581-001 Matrix: AQUEOUS Client Sample ID: RO ME Collection Date: 6/13/2013 1:30:00 PM Received Date: 6/13/2013 3:50:00 PM Analyses Result RL Qual Unib DF Date Analyzed Batch EPA METHOD 300.0: ANIONS Analyst JRR Chloride 13 0.50 myL 1 6/14/2013 11:57:32 AM R11340 Nitrogen. Nitrate (As N) ND 0.10 mg& 1 6/14/2013 11:57:32 AM R11340 Sulfate 64 10 mg& 20 6/14/2013 12:34:45 PM R11340 EPA METHOD 200.7: METALS Analyst JLF Barium ND 0.0020 rl)911- 1 6/24/2013 5:06:17 PM 7976 Beryllium ND 0.0020 mg/L 1 6/24/2013 5:06:17 PM 7976 Cadmium NO 0.0020 mg/L 1 6/2412013 5:06:17 PM 7976 Chromium ND 0.0060 mg/L 1 6/24/2013 5:06:17 PM 7978 Nickel ND 0.010 mg/L 1 6/24/2013 5:06:17 PM 7976 Sodium 110 5.0 mg& 5 62920131:17:49 PM 7976 Zoe ND 0.010 mg/L 1 6/24/2013 5:06:17 PM 7976 EPA METHOD 200.7: METALS Analyst: JLF Aluminum ND 0.10 /n94- 5 6/25/20131:34:05 PM 7976 Iron 0.050 0.020 mg/L 1 6/24/2013 5:08:39 PM 7976 Manganese ND 0.0020 mg/L 1 6/24/2013 5:08:39 PM 7976 Silver ND 0.0050 mg/L 1 6/24/2013 5:08:39 PM 7976 Zinc ND 0.010 mg/L 1 6/24/2013 5:08:39 PM 7976 EPA 200.8: METALS Analyst: DBD Antimony ND 0.®10 mg/L 1 6/25/2013 1:45.06 PM 7976 Arsenic ND 0.0010 mg/L 1 6/25/2013 1:45:06 PM 7976 Selenium ND 0.0010 mg/L 1 6/25/2013 1;45:06 PM 7976 Thallium ND 0.0010 mg/L 1 6/25/2013 1:45:06 PM 7976 EPA METHOD 245.1: MERCURY Analyst IDC Mercury ND 0.00020 mg/L 1 6/18/2013 11:40:39AM 7958 SM4500-H+B: PH Analyst: JML pH 8.22 1.68 H pH units 1 6/14/20135:36:28 PM R11333 SM2540C MOD: TOTAL DISSOLVED SOLIDS Analyst: KS Total Dissolved Solids 315 20 0 mg/L 1 6/19/2013 7:33:00 AM 7951 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: • E I 0 ft Value exceeds Maximum Contaminant Level. Value above quantitation range Analyse detected below guantitation limits RSI) is greater than RSDlimit RPD outside accepted recovery limits B 11 ND P RL Analyse detected in the associated Method Blank Holding times for preparation or analysis exceeded Not Detected at the Reporting Limit Page I of 17 Sample pH greater than 2 for VOA and TOC only. Reporting Detection Limit EFTA01124466 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306581 Date Reported: 7/3/2013 CLIENT: Zorro Ranch Project: Drinking Water ZDC Lab ID: 1306581-002 Matrix: AQUEOUS Client Sample ID: MH Kitchen Collection Date: 6/13/2013 1:40:00 PM Received Date: 6/13/2013 3:50:00 PM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 300.0: ANIONS Analyst JRR Chloride 1.4 0.50 mg/L 1 6/14/2013 12:47:09 PM R11340 Nitrogen. Nitrate (As N) ND 0.10 mg/L 1 6/14/2013 12:47:09 PM R11340 Sulfate 3.0 0.50 mg/L 1 6/14/2013 12:47:09 PM R11340 EPA METHOD 200.7: METALS Analyst JLF Barium ND 0.0020 mg& 1 6/18/2013 3:00:58 PM R11371 Beryllium ND 0.0020 mg& 1 6/18/2013 3:00:58 PM R11371 Cadmium ND 0.0020 MR 1 6/18/2013 3:00:58 PM R11371 Chromium ND 0.0060 mu& 1 6/18/2013 3:00:58 PM R11371 Nickel ND 0.010 mg/L 1 6/18/2013 3:00:58 PM R11371 Sodium 8.1 1.0 mg/L 1 6/18/2013 3:00:58 PM R11371 Zinc 0.015 0.010 mg/L 1 6/18/2013 3:00:58 PM R11371 EPA METHOD 200.7: METALS Analyst JLF Aluminum ND 0.020 mg/L 1 6/25/2013 2:11:54 PM R11552 Iron ND 0.020 mg/L 1 6/18/2013 3:03:21 PM R11371 Manganese ND 0.0020 mgt 1 6/18/2013 3:03:21 PM R11371 Silver NO 0.0050 mg/L i 6/18/2013 3:03:21 PM R11371 Zinc 0.016 0.010 RV& 1 6118/2013 3:03:21 PM R11371 EPA 200.8: METALS Analyst: DBD Antimony ND 0.0010 mon. 1 6/26/2013 1:48:43 PM R11577 Arsenic ND 0.0010 mg/1 1 6/26/2013 1:48:43 PM R11577 Selenium ND 0.0010 mg/L 1 6/28120131:48:43 PM R11577 Thallium NO 0.0010 mg/L 1 6126/2013 1:48:43 PM R11577 EPA METHOD 245.1: MERCURY Analyst: IDC Mercury ND 0.00020 mg/1. 1 6/18/201311:53:09 AM 7959 SM4500-H+B: PH Analyst JML pH 7.38 1.68 H pH units 1 6/14/2013 5:40:42 PM R11333 SM2540C MOD: TOTAL DISSOLVED SOLIDS Analyst: KS Total Dissolved Solids 31.0 20.0 mg/L 1 6/19/2013 7:33:00AM 7951 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: . E R Value exceeds Maximum Contaminant Level. Value above quantitating% range Ambit detected below quamitation limits RSD is greater than RSDlimit RPD outside accepted recovery limits B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded ND Not Detected at the Reporting Limit Page 2 ofP Sample pH greater than 2 for VOA and TOC only. RL Reporting Detection Limit EFTA01124467 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306581 Date Reported: 7/3/2013 CLIENT: Zorro Ranch Project: Drinking Water ZDC Lab ID: 1306581-003 Analyses Matrix: AQUEOUS Client Sample ID: MH Bath Collection Date: 6/13/2013 1:30:00 PM Received Date: 6/132013 3:50:00 PM Result ILL Qual Units DF Date Analyzed Batch EPA METHOD 300.0: ANIONS Analyst: JRR Chloride 1.5 0.50 mg& 1 6/14/2013 1:11:58 PM R11340 Nitrogen, Nitrate (As N) ND 0.10 mg/L 1 6/14/20131:11:58 PM R11340 Sulfate 5.2 0.50 mg/L 1 6/14/20131:11:58 PM R11340 EPA METHOD 200.7: METALS Analyst: JLF Barium ND 0 0020 mg/L 1 8/18/2013 3:05:42 PM R11371 Beryllium ND 0,0020 mg/L 1 6/18/2013 3:05:42 PM R11371 Cadmium ND 0.0020 mg/L 1 6/18/2013 3:05:42 PM R11371 Chromium ND 0.0080 mg/L 1 6/18/2013 3:05:42 PM R11371 Nickel 0.013 0.010 mg/L 1 6/18/2013 3:05:42 PM R11371 Sodium 9.0 1.0 mg/L 1 6/18/2013 3:05:42 PM R11371 Zinc 0.024 0.010 mg/L 1 6/18/2013 3:05:42 PM R11371 EPA METHOD 200.7: METALS Analyst JLF Aluminum ND 0.020 mg/1 1 6/25/2013 2:14:12 PM R11552 Iron ND 0.020 mg/L 1 W18/2013 3:08:04 PM R11371 Manganese ND 0.0020 mg/L 1 8118/2013 108:04 PM R11371 Silver ND 0.0050 mg/L 1 6/18/2013 3:08:04 PM R11371 Zinc 0.022 0.010 mg/L 1 6/1820133.08:04 PM R11371 EPA 200.8: METALS Analyst DBD Antimony ND 0.0010 mg/L 1 6/26/2013 1:53:01 PM R11577 Arsenic ND 0.0010 mg/L 1 6//20/20131:53:01 PM R11577 Selenium ND 0.0010 mg/L 1 6/26/2013 t53:01 PM R11577 Thallium ND 0.0010 mg/L 1 6/28/20131:53:01 PM R11577 EPA METHOD 245.1: MERCURY Analyst: IDC Mercury ND 0.00020 mg/L 1 8/18/201311:54:55 AM 7959 SM4500-H+B: PH Analyst. JML pH 7.50 1.68 H pH units 1 6/14/2013 5:45:23 PM R11333 SM2540C MOD: TOTAL DISSOLVED SOLIDS Analyst: KS Total Dissolved Solids 25.0 20.0 mg/L 1 6/19/2013 7:33:00 AM 7951 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Qualifiers: • Value exceeds Maximum Contaminant Level. E Value above quantitation range J Analyte detected below• quantitation limits 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits B H N P RL Analyte detected in the associated Method Blank Holding times for preparation or analysis exceeded Not Detected at the Reporting Limit Pap 3 of 17 Sample pH greater than 2 for VOA and TOC only. Reporting Detection Limn EFTA01124468 Hall Environmental Analysis Laboratory, Inc. Analytical Report Lab Order 1306581 Date Reported: 7/3/2013 CLIENT: Zorro Ranch Project: Drinking Water ZDC Lab ID: 1306581-004 Matrix: AQUEOUS Client Sample ID: RC Kitchen Collection Date: 6/13t2013 1:30:00 PM Received Date: 6/13/2013 3:50:00 PM Analyses Result RL Qual Units DF Date Analyzed Batch EPA METHOD 300.0: ANIONS Chloride Nitrogen, Nitrate (As N) Sulfate EPA METHOD 200.7: METALS Barium Beryllium Cadmium Chromium Nickel Sodium Zinc EPA METHOD 200.7: METALS Aluminum Iron Manganese Silver Zinc EPA 200.8: METALS Antimony Arsenic Selenium Thallium EPA METHOD 245.1: MERCURY Mercury SM4500-E1+8: PH 1.3 pH 0.50 mg/L ND 0.10 mg/L 6.9 0.50 mg/L 0.010 ND NO ND ND 28 0.033 ND 0041 ND ND 0.029 SM2540C MOD: TOTAL DISSOLVED SOLIDS Total Dissolved Solids ND ND ND ND ND 0.0020 mg/L 0.0020 mg/L 0.0020 mg/L 0.0060 mg/L 0.010 mg/L 1.0 mg/I 0.010 InWI- 0.020 mg/L 0.020 mg/L 0.0020 mg/L 0.0050 mg/L 0.010 mgA_ 0.0010 mg/L 0.0010 mg/L 0.0010 mg/L 0.0010 mg& 0.00020 mg/L 7.58 1.68 H pH units 32.0 20.0 mg/L 1 1 Analyst JRR 6/14/2013 1:36:47 PM R11340 6/14/20131:36:47 PM R11340 6/14/2013 1:36:47 PM R11340 Analyst. JLF 6/18/2013 3:10:25 PM 6/18/2013 3:1025 PM 6282013 3:1025 PM 6/1&20133:10:25 PM 6118/20133:10:25 PM 6/18/2013 3:1025 PM 6/18/2013 3:1025 PM Analyst: 1 6/25/2013 2:16:29 PM 1 6/18/2013 3:12:49 PM 1 6/11312013 3:12:49 PM 1 6/18/2013 3:12:49 PM 1 6/18/2013 3:12:49 PM R11371 R11371 R11371 R11371 R11371 R11371 R11371 JLF R11562 R11371 R11371 R11371 R11371 Analyst: DBD 1 62620131:5720 PM R11577 1 6/26/2013 1:57:20 PM R11577 1 6/26/20131:5720 PM R11577 1 6/26120131:5720 PM R11577 Analyst IDC 1 6/18/2013 11:56:41 AM 7959 Analyst JML 1 6/14/2013 5:49:42 PM R11333 Analyst: KS 1 6/19/2013 7:33:03 AM 7951 Refer to the QC Summary report and sample login checklist for flagged QC data and preservation information. Onallflers • E R Value exceeds Maximum Contaminant Level. Value above quantization range Analyte detected below quantization limits RSD is greater than RSDI imit RPD outside accepted recovery limits B ND P RL Analyte detected in the associated Method Blank Holding times for preparation or analysis exceeded Not Detected at the Reporting Limit Page 4 of 17 Sample pH greater than 2 for VOA and TOC only. Reporting Detection limit EFTA01124469 Chain-of ustody Record Tum- und Time: O Rush HALL ANALYSIS ENVIRONMENTAL LABORATORY NE - Albuquerque, NM 87109 Fax 505 345-4107 Client:42o(VCD Standard 4901 Hawkins Tel. 505-345-3975 Project Name: 2.,De_. Mating Addroey_kfil ;two 641 Q:1-"Lion\-si 0 t)A .6i Project #: Phone #: C Ca4 CPI Analysis Request email or Fax#: Project Manager: el-tOR36,Th — o CO ,to CO 2 l-+ Z + Icii -1os CO O r a. 3-+ 2• 6 Ice 2 O cc O — c< 0 int ; 2 ez c---o:i r .0`r 2 r‘ - - °z --- •4;s), ;lot' ti 2 0"; " El (-7) 2 in r9- tine‘l,-: Cc 2 — I g_ ,,, a' Pc d w a az 6 (5"z LC en g 0, co o a. a co co.,,.8 IF,' cticv, 2 .5 — c;c332 ,t, ca p.2 Cn 2 >--75 o m . eL QA/QC Package: O Standard O Level 4 (Full Validation) .----&10.--Q..,___ Accreditation O NELAP O Othe 1 Samplgtly r... ilala?•-.! -,t I' ,i, te ,ti.iu.i O ELM (Type) Date P p S Time I 761) Matrix Pev Sample Request ID a° kA ‘-‘ Container Type and ti Preservative Type 1 - , 1 - co i %.z g )\ lni \ -IQ Pry \-kk.k Vkkkd(On —ntya_. y ?..s 7/ 1\13 1 "A) f-il1(\`AV\ Cbakh ---O0 5 )9‹ I\ I3 1'3D tclrW.., \KA-6&-). —coq )(<?( ( Date: 1)1 3 Time: Rellnquished by: leg) 6 g€En Rec ed by Date Ire ,.. Aie_srd, Remarks: D to: Time: RON ished by: ed by: Dole Time H necessary. eampke submitted to HAS Enylrocin-eoltO may be setcoutracted to oat.% accuthted labomtodos. Thm servos as nal' x of fht possibility. Any cub-contracted data roil be deafly notated on the anulylio* report EFTA01124470 HALL ENVIRONMENTAL ANALYSIS LABORATORY Nall ErntontaentalAnalnis Laboratory 4901 Hahn NE Albuquerque, NM 87105 TEL 505445-3975 FAX: SOS-345-410; Waite: www.hallorvironstentaLcorx Sample Log-In Check List Client Name: ZORRO RANCH Work Order Number 1306581 RcotNo Received by/date: Logged By: Michelle Garcia 6/1312013380:00 PM Completed By: Michelle Garcia 6/13/2013 424:29 PM Revlevred By: 1O 06/i q//5 Chain of Custody 1. Custody seals Intact on sample bottles? Yes O No _ Not Presoit W, 2. Is Charn of Custody complete? Yes 0 No Not Presert L 3 How vats tho Sa male derNefed? Met fit ALL eitmo;L> 4r1ithab eituu,) Loq In 4. Was an attempt made to cool the samples? 5. Were ell samples received et a temperature of >0' C to 6.0•C 6. Sample(s) in proper container(s)? 7. Sufficient sample volume for indicated test(s)? 8. Are samples (except VOA and ONG) properly preserved? 9. Was preservative added to bottles? 10.VOA vials have zero headspace? 11. Were any sampe conta oars received broken? 12.0oes paperwork match Dottie labels? (Note discrepancies on chain Of custody) 13. Are matrices correctly identified on Chain of Custody? 14. le it dear what analyses were requested? 15. Were all holding times able to be met? (If no, notify customer for authorization.) Yes Ni No EJ Yes 7 No Not required Yes -.Vel No O Yes }VI No O Yes :it No O Yea n No Yes O No O Yes U No Yes NO O Yee No O Yes d No O Yes k No D Special Handling (if applicable) 16. Was client notified of all discrepancies with this orderg Yee O 14A O NA ❑ NA El No VOA Vials * of preserved bottles checked for pH CAW& by: 2 unties muted) No O m Person Nettled: r7 . pellc By Whom: bIL O dal ❑ MOM ❑ FIX O M Person Regarding: Client Instructions: 17. Additional remarks: 18. Cooler Infomvitioq CoelerNo-I.TemP°C I Condition I Seal hltiCt !Seal No SealDe1e StmeLBY 1 62.3 ;Good Idol Present Page I of 1 EFTA01124471