Spin-relaxation and magnetoresistance in FM/SC/FM tunnel junctions

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Saburo Takahashi, Taro Yamashita, Hiroshi Imamura, Sadamichi Maekawa

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Spin-relaxation and magnetoresistance in FM/SC/FM tunnel junctions 

S. Takahashi a T. Yamashita a , H. Imamura b , and S. Maekawa a 

a Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan 

b Graduate School of Information Sciences, Tohoku University, Sendai 980-8579, Japan 






The effect of spin relaxation on tunnel magnetoresistance (TMR) in a ferromagnet/superconductor/ferromagnet 
(FM/SC/FM) double tunnel junction is theoretically studied. The spin accumulation in SC is determined 
by balancing of the spin-injection rate and the spin-relaxation rate. In the superconducting state, the spin- 
relaxation time t s becomes longer with decreasing temperature, resulting in a rapid increase of TMR. The TMR 
of FM/SC/FM junctions provides a useful probe to extract information about spin-relaxation in superconductors. 



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Spin-polarized tunneling plays an important 
role in the spin-dependent transport of magnetic 
nanostructures GJ. The spin-polarized electrons 
injected from ferromagnets (FM) into nonmag- 
netic metals (NM) such as a normal metal, semi- 
conductor, and superconductor creates a nonequi- 
librium spin polarization in NM &-§. The effi- 
cient spin injection and weak spin-relaxation dur- 
ing transport are required for practical applica- 
tions. A number of experiments for observing the 
spin relaxation time r s in SCs has been reported 
by using a spin-injection device || and by the 
conduction electron spin resonance PjlQ]. 

A double tunnel junction FM/SC/FM contain- 
ing superconductor (SC) sandwiched between two 
FMs is a unique system to investigate nonequi- 
librium phenomena caused by spin injection, es- 
pecially the magnetoresistive effects by compe- 
tition between superconductivity and spin accu- 
mulation |]ll]— [l^] . The pronounced magnetoresis- 
tance effects is brought about by a long spin relax- 
ation time t s in SC, which corresponds to a long 
spin-diffusion length. In this article, we take into 
account the coherence effect of superconductivity 
on the spin-relaxation due to spin-orbit scattering 
by impurities |lq | , and demonstrate that the tun- 
nel magnetoresistance (TMR) of the FM/SC/FM 
junction exhibits a large enhancement due to the 
increase of t s in the superconducting state. 

We consider a FM/SC/FM double tunnel junc- 
tion. The left and right electrodes are made of a 
ferromagnet, and the central one is a supercon- 



ductor with thickness d smaller than the spin- 
diffusion length As . The magnetizations of FMs 
are aligned either parallel or antiparallcl. Using 
the Fermi's golden rule, we calculate the spin- 
dependent tunnel currents across the junctions 
jll| . |Rql . In the following we consider the case that 
the bias voltage V is much smaller than the su- 
perconducting gap parameter A. In this case, the 
shift of chemical potential Sfi for up-spin (— 6fi for 
down-spin) electrons due to spin accumulation is 
much smaller than A, so that the tunnel current 
If across the «th junction (z = 1, 2) becomes 

ll(V) = Glx(T)[V/2-6n/e], (1) 

li(V) = G[x(T)[V/2- 



4(V)=Glx(T)[V/2- 
lhV) = Gix(T)[V/2 



<We] , (2) 

Sii/e] , (3) 

- We] ■ (4) 

Here, Gfx(T) (i — 1, 2) is the tunnel conductance 
for electrons with spin <r in the superconducting 
state, Gf is that in the normal state, and 

E k ( df 



X(T) = 2 f 
Ja 



<M 



dE v 



dE^ 



(5) 



where fo(Ek) is the Fermi distribution function 
and Ek — y^ + A 2 the dispersion of quasipar- 
ticles, £k being one-electron energy relative to the 
chemical potential. 

The spin density S accumulated in SC is de- 
termined by balancing the spin injection rate 
{dS/dt) h - with the spin relaxation rate S/t s : 



{I 1] -I n )-{I 2] -hi) = 2eS/T s 



(6) 



where t s is the spin relaxation time and 

S = \ E [/T (^k) - h (#k)] « N(0) X {T)Sn, (7) 

k 

where / <T (£ , k ) ~ /oC%) - (df /dE k )cj5n is the 
distribution function of quasiparticles with spin 
a and iV(0) is the normal-state density of states 
in SC. 

It follows from Eqs. |l])-(0) that the tunnel cur- 
rents for the parallel (P) and antiparallel (AP) 
alignments are given by 



Iap 



X (T)V/R T , 

i - p 2 + r s 

i + r s 



X (T)V/Ri 



(8) 
(9) 



where R T = 1/G T (G T = Gj + GJ) is the tunnel 
resistance and T s is the relaxation parameter 

T s = e 2 N(0)R T Ad/r s , (10) 

with A being the junction area. Therefore, we 
have the TMR ratio at low bias (V< A) 

I P - J AP P 2 



Iai 



l-P 2 



11 



where P = {G\ - G\)/{G]+G\) is the tunnel- 
ing spin polarization. For a weak spin relaxation 
(r s « 1), TMR = P 2 /(1-P 2 ), while for a strong 
spin-relaxation (T s > 1), TMR = P 2 /T s < 1. 

In SC, the spin relaxation is caused by the spin- 
orbit scattering from impurities or grain bound- 
aries. The spin-orbit interaction TL so via impurity 
potential V; mp (r) is given by 

H a0 = -i(h/2mc) 2 a • [VMmp(r) X V] , (12) 

where a is the Pauli spin matrix. The scattering 
matrix elements over quasiparticle states |kcr) has 
the form: 



(kV|W so |ker) = i\ so Vk<u ovv • (k X k' 



(13) 



where A so is the spin-orbit coupling parameter, 
Vk'k = (wk'^k - Wk'^k) V imp , |w k | 2 = 1 - M 2 = 
\ (1 + £k/Ek), and k = k/|k|. Using the golden 
rule formula, we obtain the spin-relaxation rate 
due to the spin- flip scattering by H. so : 



f) =Y ni £ l(k ' i|Ko|kT>|2 ^ k 

/ sf k / k 



Ek>) 




0.5 1 

Temperature (T/T c ) 

Figure 1 . Temperature dependence of the spin- 
relaxation time Ty. Inset shows x(T) and 2/o(A) 
versus T, which are used to calculate r s . 



8A 2 o 7V(0) 



9r; 



x [fi(Ev) - / T (£ k )] 
/ [/ T (^k)-/i(^k)]^k, (14) 

J A 



where 1/Th 



imp J A 

(2ir/h) ni V 2 N(0) is the scat- 



'imp -- v~"/ "v'"i ' lmp ' 

tering rate by impurities and 7ij is the impurity 
concentration. 

From Eqs. ([7j) and (|14|), we determine the re- 
laxation time t s from (dS/dt) si = —S/t s , and 
obtain 



r s r 



/: 



A ^E't-A- 



[f^E)-f l (E)]dE 



J™lME)-fl(E)]dE 



(15) 



where t s { = 9T imp /8A 2 is the spin-flip scattering 
time in the normal state. Note that the expres- 
sion of Eq. ( |15| ) is valid for vpr s f 3> £o — frvp/ir/S.0 
Q. For 5/x < A, Eq. @ reduces to 



[ X (T)/2/ (A)]t s 



sf. 



(16) 



which is the same as the result of Yafet |15| , but 
differs from the result of Zhao and Hershfield [Hj . 
Equation ([15|) is a generalization of Yafet to the 
case of arbitrary value of Sfi. 

The temperature dependence of the spin- 
relaxation parameter T s is scaled to the normal- 
ized spin-relaxation time t s /t s { by the relation 
T s = (r sf /r s )rf, where T^ = e 2 N{0)R T Ad/T sf 
is the relaxation parameter in the normal state. 
Figure 1 shows the temperature dependence of 



H 
H 





1 1 1 1 1 




— ^ZL_ ' ' 


■ 


" \\ 8 10 


N. - E 




i \\ s 

I \V Hi 


normal state \ 


: 


■ \ V\co 


(T=T C ) \e 


: 


0.1 1 10 100 ■ 

r N 

1 s 


L \20\x 


- 


:\. 5^C^ 


c>.. 


^-^2^^^ 


~~ ^^5^ ~ 


: r^ 


^^^^^ 





P = 0.5 : 


■ 






0.5 

T/X- 



Figure 2. Tunnel magnetoresistance as a func- 
tion of temperature for different value of the re- 
laxation parameter. Inset shows the TMR versus 
T^ in the normal state. 



r s /r s f. Above T = T c , the spin relaxation time 
r s coincides with the spin- flip scattering time r S £ . 
As temperature T is lowered below T c , t s be- 
comes longer with decreasing T and behaves as 
t s ~ (nA/2k B T) 1 / 2 T si at low T. 

Figure 2 shows the temperature dependence of 
the normalized TMR for different values of T™. 
The inset shows the TMR versus T^ in the nor- 
mal state. In the case of T^ > 1, which corre- 
sponds to the case that the spin-relaxation rate 
is larger than the spin-injection rate in the nor- 
mal state, the TMR above T c is suppressed com- 
pared with the optimal value 33% for T™ = and 
P = 0.5 as shown in the inset of Fig. 2. How- 
ever, in the superconducting state below T c , the 
TMR increases rapidly with decreasing T due to 
the increase of r s , and recovers the optimal TMR 
in the limit of T — ► 0. If one uses the values 
of R T A = 100 ft/im 2 , r sf = 10- 10 sec, d = 10 
nm, and N(Q) = 10 22 /(eVcm 3 ), then one obtains 
r^ 1 = 10. Notice that in the case of strong spin- 
relaxation (r^ 3> 1), the TMR becomes propor- 
tional to t s , so that the temperature dependence 



of TMR/TMR(T C ) coincides with that of t s /t s[ 
as shown by the dashed curve in Fig. 2. The result 
indicates that the TMR of FM/SC/FM junctions 
provides a method to extract important informa- 
tion about spin-relaxation in superconductors. 

The authors are grateful to A. Fert and 
M. Johnson for fruitful discussions. A part 
of this work was done during stay (S.T.) in 
CNRS/Thomson-CSF, France. This work is sup- 
ported by a Grant-in- Aid for Scientific Research 
from Ministry of Education. S.M. acknowledges 
support of the Humboldt Foundation. 

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